The role of bismuth in the SOHIO process

被引：126
作者：
Hanna, TA [1 ]
机构：
[1] Texas Christian Univ, Dept Chem, Ft Worth, TX 76129 USA
来源：
COORDINATION CHEMISTRY REVIEWS | 2004年 / 248卷 / 5-6期
基金：
美国国家科学基金会;
关键词：
bismuth; SOHIO process; homogeneous model systems; molybdenum; oxidation catalysis; ammoxidation catalysis;
D O I：
10.1016/j.ccr.2003.10.001
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The Standard Oil of Ohio Company (SOHIO) process is the oxidation/ammoxidation of propene over bismuth/molybdate catalysts. Studies in the heterogeneous systems show that bismuth is involved in the rate-determining hydrogen abstraction from propene in both cases, and may be involved in later steps of the process as well. Model studies support the intervention of bismuth(III) in the rate-determining step and molybdenum(VI) in later steps. Few model studies with bismuth-containing compounds have been reported. (C) 2004 Elsevier B.V. All rights reserved.
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页码：429 / 440
页数：12
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