Extraction and separation of Pt(IV)/Rh(III) from acidic chloride solutions using Aliquat 336

被引:71
作者
Lee, Jin-Young [1 ]
Kumar, J. Rajesh [1 ]
Kim, Joon-Soo [1 ]
Kim, Dong-Jin [1 ]
Yoon, Ho-Sung [1 ]
机构
[1] Korea Inst Geosci & Mineral Resources KIGAM, Mineral Resources Res Div, Met Recovery Dept, Taejon 305350, South Korea
关键词
Extraction and separation; Pt(IV); Rh(III); Aliquat; 336; LIQUID-LIQUID-EXTRACTION; SOLVENT-EXTRACTION; HYDROCHLORIC-ACID; AQUEOUS-SOLUTIONS; PRECIOUS METALS; PLATINUM; PALLADIUM; RHODIUM; RECOVERY; IRIDIUM;
D O I
10.1016/j.jiec.2008.12.006
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Extraction and separation of Pt(IV)/Rh(III) from chloride solutions using Aliquat 336 (Quaternary ammonium salt made by the methylation of mixed tri octyl/decyl amine) diluted in kerosene as an extractant/synergist alone and mixed with organophosphorous extractants as synergists/extractants were carried out from an aqueous feed containing 0.0005 mol L(-1) Pt(IV)/Rh(III). Variation of hydrochloric acid concentration of aqueous phase from 0.005 to 10.0 mol L(-1) increased the percentage extraction of platinum up to 5.0 mol L(-1) there after it decreases. Whereas in the case of rhodium, from 0.005 to 1.0 mol L(-1) acid range the percentage extraction was decreased from 1.0 to 10.0 mol L(-1) acid range is favorable for extraction. Platinum(IV)/rhodium(III) separation factor of 279.2 was obtained at 1.0 mol L(-1) HCl concentration with 0.005 mol L(-1) Aliquat 336 and separation factor of 612.3 was obtained at 3.0 mol L(-1) HCl concentration with 0.01 mol L(-1) Aliquat 336. The present study optimized the various experimental parameters like phase contact time, effect of extractant, salts, temperature, loading capacity of extractant, stripping studies with various mineral acids/bases, recycling and reusing capacity of extractant up to ten cycles. (C) 2009 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:359 / 364
页数:6
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