Synergy in the Catalytic Activity of Bimetallic Nanoparticles and New Synthetic Methods for the Preparation of Fine Chemicals

被引:68
作者
Francesco, Irene Notar [1 ]
Fontaine-Vive, Fabien [1 ]
Antoniotti, Sylvain [1 ]
机构
[1] Univ Nice Sophia Antipolis, CNRS, UMR 7272, Inst Chim Nice, F-06108 Nice 2, France
关键词
alloys; heterogeneous catalysis; nanoparticles; palladium; sustainable chemistry; DENSITY-FUNCTIONAL THEORY; AU-PD; GOLD NANOPARTICLES; AEROBIC OXIDATION; HETEROGENEOUS CATALYSTS; TRANSITION-METAL; ALLOY CATALYSTS; CARBON-CARBON; FORMIC-ACID; ALCOHOLS;
D O I
10.1002/cctc.201402252
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Metal nanoparticles receive tremendous interest as alternative catalysts in a quest to fill the gap between homogeneous and heterogeneous catalysis with selective and sophisticated reactions that occur in highly recyclable and scalable processes. In this area of research that is growing rapidly, we would like to focus on bimetallic nanoparticles and on how these particular materials have been used recently as nanocatalysts in fine-chemicals synthesis and transformations. The synergistic effects observed with these nanocatalysts, either as nanoalloys or core-shell objects, that accounts for their superior activity and efficiency are discussed.
引用
收藏
页码:2784 / 2791
页数:8
相关论文
共 75 条
[31]   Magnetic copper-iron nanoparticles as simple heterogeneous catalysts for the azide-alkyne click reaction in water [J].
Hudson, Reuben ;
Li, Chao-Jun ;
Moores, Audrey .
GREEN CHEMISTRY, 2012, 14 (03) :622-624
[32]  
Hutchings G.J., 2014, ANGEW CHEM-GER EDIT, V126, P2413
[33]   Simple synthesis of Pd-Fe3O4 heterodimer nanocrystals and their application as a magnetically recyclable catalyst for Suzuki cross-coupling reactions [J].
Jang, Youngjin ;
Chung, Jooyoung ;
Kim, Seyoung ;
Jun, Samuel Woojoo ;
Kim, Byung Hyo ;
Lee, Dong Won ;
Kim, B. Moon ;
Hyeon, Taeghwan .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2011, 13 (07) :2512-2516
[34]   Recent progress in synergistic catalysis over heterometallic nanoparticles [J].
Jiang, Hai-Long ;
Xu, Qiang .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (36) :13705-13725
[35]   Synergistic Catalysis of Au@Ag Core-Shell Nanoparticles Stabilized on Metal-Organic Framework [J].
Jiang, Hai-Long ;
Akita, Tomoki ;
Ishida, Tamao ;
Haruta, Masatake ;
Xu, Qiang .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (05) :1304-1306
[36]   Remarkable Effect of Bimetallic Nanocluster Catalysts for Aerobic Oxidation of Alcohols: Combining Metals Changes the Activities and the Reaction Pathways to Aldehydes/Carboxylic Acids or Esters [J].
Kaizuka, Kosuke ;
Miyamura, Hiroyuki ;
Kobayashi, Shu .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (43) :15096-15098
[37]   Magnetically Recoverable CuFe2O4 Nanoparticles: Catalyzed Synthesis of Aryl Azides and 1,4-Diaryl-1,2,3-triazoles from Boronic Acids in Water [J].
Kumar, A. Suresh ;
Reddy, M. Amarnath ;
Knorn, M. ;
Reiser, O. ;
Sreedhar, B. .
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2013, 2013 (21) :4674-4680
[38]   Synthesis of supported Ni@(RhNi-alloy) nanocomposites as an efficient catalyst towards hydrogen generation from N2H4BH3 [J].
Li, Changming ;
Dou, Yibo ;
Liu, Jie ;
Chen, Yudi ;
He, Shan ;
Wei, Min ;
Evans, David G. ;
Duan, Xue .
CHEMICAL COMMUNICATIONS, 2013, 49 (85) :9992-9994
[39]  
Li L., 2013, ANGEW CHEM INT EDIT, V125, P11255, DOI DOI 10.1002/ANGE.201303912
[40]   Pd-Cu2O and Ag-Cu2O Hybrid Concave Nanomaterials for an Effective Synergistic Catalyst [J].
Li, Lingling ;
Chen, Xiaobin ;
Wu, Yuen ;
Wang, Dingsheng ;
Peng, Qing ;
Zhou, Gang ;
Li, Yadong .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (42) :11049-11053