Synergy in the Catalytic Activity of Bimetallic Nanoparticles and New Synthetic Methods for the Preparation of Fine Chemicals

被引:68
作者
Francesco, Irene Notar [1 ]
Fontaine-Vive, Fabien [1 ]
Antoniotti, Sylvain [1 ]
机构
[1] Univ Nice Sophia Antipolis, CNRS, UMR 7272, Inst Chim Nice, F-06108 Nice 2, France
关键词
alloys; heterogeneous catalysis; nanoparticles; palladium; sustainable chemistry; DENSITY-FUNCTIONAL THEORY; AU-PD; GOLD NANOPARTICLES; AEROBIC OXIDATION; HETEROGENEOUS CATALYSTS; TRANSITION-METAL; ALLOY CATALYSTS; CARBON-CARBON; FORMIC-ACID; ALCOHOLS;
D O I
10.1002/cctc.201402252
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Metal nanoparticles receive tremendous interest as alternative catalysts in a quest to fill the gap between homogeneous and heterogeneous catalysis with selective and sophisticated reactions that occur in highly recyclable and scalable processes. In this area of research that is growing rapidly, we would like to focus on bimetallic nanoparticles and on how these particular materials have been used recently as nanocatalysts in fine-chemicals synthesis and transformations. The synergistic effects observed with these nanocatalysts, either as nanoalloys or core-shell objects, that accounts for their superior activity and efficiency are discussed.
引用
收藏
页码:2784 / 2791
页数:8
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