Six transition metal-organic materials with the ditopic 4,4′-diaminodiphenylmethane ligand: Synthesis, structure characterization and luminescent properties

被引：4

作者：

Chisca, Diana ^{[1
,2
]}

Croitor, Lilia ^{[1
]}

Melnic, Elena ^{[1
]}

Petuhov, Oleg ^{[3
,4
]}

Kulikova, Olga ^{[1
]}

Fonari, Marina S. ^{[1
]}

机构：

[1] Inst Appl Phys, Acad Str 5, MD-2028 Kishinev, Moldova

[2] Tiraspol State Univ, Iablocikin Str 5, MD-2069 Kishinev, Moldova

[3] Inst Chem, Acad Str 3, MD-2028 Kishinev, Moldova

[4] Inst Geol & Seismol, Gheorghe Asachi Str 60-3, MD-2028 Kishinev, Moldova

来源：

POLYHEDRON | 2020年 / 192卷

关键词：

4,4 '-Diaminodiphenylmethane; Transition metal; IR spectroscopy; X-ray; Luminescence;

D O I：

10.1016/j.poly.2020.114844

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Six coordination compounds based on 4,4'-diaminodiphenylmethane (dadpm) and different salts (acetates, nitrates and perchlorates) of four (Ni, Co, Zn, Cd) transition metals have been prepared and characterized by IR spectroscopy, thermogravimetric analysis, and single-crystal X-ray diffraction methods. The crystalline solids include four monomers: [Co(dadpm)(2)(CH3COO)(2)(H2O)(2)] (1), [Cd(dadpm)(2)(CH3COO)(2)(H2O)(2)] (2), [Zn(dadpm)(4)(H2O)(2)](NO3)(2)(H2O)(2) (3), [Ni(dadpm)(3)(dmf)(H2O)(2)] (ClO4)(2)(dadpm)(H2O) (4), and two one-dimensional coordination polymers: {[Cd(dadpm)(2)(H2O)(ClO4)] (ClO4)}n (5) and {[Cd(dadpm)(4)](ClO4)(2)}(n) (6). The transition metals used in this study accommodate two, three, four and six dadpm ligands in the coordination cores. The luminescence properties for six coordination compounds are reported. (c) 2020 Elsevier Ltd. All rights reserved.

引用

页数：10

共 22 条

[11]

Macrae CF, 2006, J APPL CRYSTALLOGR, V39, P453, DOI 10.1107/S0021 88980600731X

[12] trans-Diaquatetrakis(4,4′-methylenediphenyl-amine-κN)cobalt(II) dinitrate dihydrate [J].

Nordell, KJ ;

Schultz, KN ;

Smith, MD .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2004, 60 :M857-M858

[13] The interplay of coordinative, hydrogen bonding and π-π stacking interactions in sustaining supramolecular solid-state architectures.: A study case of bis(4-pyridyl)- and bis(4-pyridyl-N-oxide) tectons [J].

Roesky, HW ;

Andruh, M .

COORDINATION CHEMISTRY REVIEWS, 2003, 236 (1-2) :91-119

[14] A new luminous hexacoordinated coordination polymer of cadmium(II) containing benzidine and dicyanamide as bridging units [J].

Satapathi, Smita ;

Chattopadhyay, Soumi ;

Bhar, Kishalay ;

Das, Sumitra ;

Kumar, Ramachandran Krishna ;

Maji, Tapas Kumar ;

Ghosh, Barindra Kumar .

INORGANIC CHEMISTRY COMMUNICATIONS, 2011, 14 (05) :632-635

[15] A short history of SHELX [J].

Sheldrick, George M. .

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122

[16]

Sheldrick GM, 2015, ACTA CRYSTALLOGR C, V71, P3, DOI [10.1107/S2053229614024218, 10.1107/S2053273314026370, 10.1107/S0108767307043930]

[17]

Tiekink J.-Z.-S.-R.-T., 2012, IMPORTANCE PI INTERA, V2nd

[18]

Wang RH, 2004, CHINESE J STRUC CHEM, V23, P403

[19] 1-D Structures of assemblies containing oxamidato dicopper building blocks controlled by ditopic N-donor spacers [J].

Zhang, HX ;

Kang, BS ;

Zhou, ZY ;

Chan, ASC ;

Chen, ZN ;

Ren, C .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2001, (10) :1664-1669

[20] Structure, spectral and thermal properties of 4,4′-diaminodiphenylmethane nickel(II) complex:: [Ni(CH2(C6H4NH2)2)4(H2O)2](NO3)2•2H2O [J].

Zhang, Y ;

Lei, Z ;

Jianmin, L ;

Nishiura, M ;

Imamoto, T .

JOURNAL OF MOLECULAR STRUCTURE, 2001, 559 (1-3) :55-58

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