Synthesis of novel bisoxazoline ligands for the enantioselective Diels-Alder reaction

被引：0

作者：

Bian, Qing Hua ^{[1
]}

Liu, Jun ^{[1
]}

Yin, Ming Ming ^{[1
]}

Wang, Min ^{[1
]}

机构：

[1] China Agr Univ, Coll Sci, Beijing 100094, Peoples R China

来源：

CHINESE CHEMICAL LETTERS | 2006年 / 17卷 / 08期

关键词：

asymmetry catalytic; bisoxazoline; Diels-Alder reaction; ligand;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Four novel bisoxazoline ligands 8a-d were synthesized from (S)-amino alcohols and could be formed effective catalysts (up to 77% ee for endo isomer) with Cu(OTf)(2) for enantioselective Diels-Alder addition. The facility of the reaction was dependent on the nature of the substituent R in the bisoxazoline ligand.

引用

页码：1033 / 1036

页数：4

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