High-resolution stimulated Raman spectroscopy and analysis of the ν2, ν5 and 2ν6 bands of 34SF6

被引：14

作者：

Boudon, V.

Domenech, J. L.

Ramos, A.

Bermejo, D.

Willner, H.

机构：

[1] Univ Bourgogne, Phys Lab, CNRS, UMR 5027, F-21078 Dijon, France

[2] CSIC, Inst Estructura Mat, E-28006 Madrid, Spain

[3] Berg Univ Wuppertal, Fachbereich Anorgan Chem 9, D-42097 Wuppertal, Germany

来源：

MOLECULAR PHYSICS | 2006年 / 104卷 / 16-17期

关键词：

D O I：

10.1080/00268970600722921

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The nu(2), nu(5) and (2)nu(6) regions of (SF6)-S-34 have been studied by stimulated Raman spectroscopy. We used an isotopically pure sample of (SF6)-S-34. A detailed analysis of the nu(2) and nu(5) fundamentals has been performed with the HTDS program suite (http://www.u-bourgogne.fr/LPUB/ hTDS.html) dedicated to octahedral XY6 molecules. We also present a preliminary analysis of the (2)nu(6) band for both (SF6)-S-32 and (SF6)-S-34. Finally, we give the S-32 - S-34 isotopic shifts for all the SF6 fundamentals.

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页码：2653 / 2661

页数：9

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