Anionic ring-opening polymerization of a strained phosphirene: A route to polyvinylenephosphines

被引：28

作者：

Vanderark, Lawrence A.

Clark, Timothy J.

Rivard, Eric

Manners, Ian

Slootweg, J. Chris

Lammertsma, Koop

机构：

[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

[2] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada

[3] Vrije Univ Amsterdam, Fac Sci, Dept Chem, NL-1081 HV Amsterdam, Netherlands

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 31期

关键词：

D O I：

10.1039/b606311j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A strained 1-phenyl-2,3-dimethylphosphirene undergoes anionic ring-opening polymerization upon initiation with n-butyl lithium at ambient temperature to yield polyvinylenephosphine, an unsaturated organophosphorus polymer.

引用

页码：3332 / 3333

页数：2

共 30 条

[1] A new, efficient, and in some cases highly regioselective water-soluble polymer rhodium catalyst for olefin hydroformylation [J].

Ajjou, AN ;

Alper, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (07) :1466-1468

[2]

Archer R.D., 2001, SPEC TOP INOR CHEM, P179

[3] The dithieno[3,2-b:2′,3′-d]phosphole system:: A novel building block for highly luminescent π-conjugated materials [J].

Baumgartner, T ;

Neumann, T ;

Wirges, B .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (45) :6197-6201

[4] The circumambulation of a phosphirane: Taking 9-phenyl-9-phosphabicyclo[6.1.0]nona-2,4,6-triene for a "walk" [J].

Bulo, RE ;

Jansen, H ;

Ehlers, AW ;

de Kanter, FJJ ;

Schakel, M ;

Lutz, M ;

Spek, AL ;

Lammertsma, K .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (06) :714-717

[5] Synthesis and self-assembly of the organic-organometallic diblock copolymer poly(isoprene-b-ferrocenylphenylphosphine):: Shell cross-linking and coordination chemistry of nanospheres with a polyferrocene core [J].

Cao, L ;

Manners, I ;

Winnik, MA .

MACROMOLECULES, 2001, 34 (10) :3353-3360

[6]

Chunechom V, 1998, ANGEW CHEM INT EDIT, V37, P1928, DOI 10.1002/(SICI)1521-3773(19980803)37:13/14<1928::AID-ANIE1928>3.0.CO

[7]

2-0

[8] Transition metal-catalyzed formation of phosphorus-boron bonds: A new route to phosphinoborane rings, chains, and macromolecules [J].

Dorn, H ;

Singh, RA ;

Massey, JA ;

Nelson, JM ;

Jaska, CA ;

Lough, AJ ;

Manners, I .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (28) :6669-6678

[9] THE H-1, C-13 AND P-13 NMR-SPECTRA OF EZ PAIRS OF SOME PHOSPHORUS SUBSTITUTED ALKENES [J].

DUNCAN, M ;

GALLAGHER, MJ .

ORGANIC MAGNETIC RESONANCE, 1981, 15 (01) :37-42

[10]

Gates DP, 2005, ANN R CH IN, V100, P489

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