Metal-Organic Framework@Microporous Organic Network: Hydrophobic Adsorbents with a Crystalline Inner Porosity

被引：210
作者：
Chun, Jiseul [1 ,2 ]
Kang, Sungah [1 ,2 ]
Park, Nojin [1 ,2 ]
Park, Eun Ji [1 ,2 ]
Jin, Xing [1 ,2 ]
Kim, Kwang-Dae [1 ,2 ]
Seo, Hyun Ook [1 ,2 ]
Lee, Sang Moon [1 ,2 ]
Kim, Hae Jin [3 ]
Kwon, Woo Hyun [4 ]
Park, Young-Kwon [4 ]
Kim, Ji Man [1 ,2 ]
Kim, Young Dok [1 ,2 ]
Son, Seung Uk [1 ,2 ]
机构：
[1] Sungkyunkwan Univ, Dept Chem, Suwon 440746, South Korea
[2] Sungkyunkwan Univ, Dept Energy Sci, Suwon 440746, South Korea
[3] Korea Basic Sci Inst, Taejon 350333, South Korea
[4] Univ Seoul, Grad Sch Energy & Environm Syst Engn, Seoul 130743, South Korea
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2014年 / 136卷 / 19期
关键词：
COPPER COMPLEXES; ANODE MATERIALS; SURFACE-AREA; ADSORPTION; UIO-66; POLYMERS; SEPARATION; CO2; STABILITY; STORAGE;
D O I：
10.1021/ja500362w
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This work reports the synthesis and application of metal-organic framework (MOF)@microporous organic network (MON) hybrid materials. Coating a MOF, UiO-66-NH2, with MONs forms hybrid microporous materials with hydrophobic surfaces. The original UiO-66-NH2 shows good wettability in water. In comparison, the MOF@MON hybrid materials float on water and show excellent performance for adsorption of a model organic compound, toluene, in water. Chemical etching of the MOF results in the formation of hollow MON materials.
引用
收藏
页码：6786 / 6789
页数：4
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