Thermodynamics of Molecules Strongly Coupled to the Vacuum Field

被引：66

作者：

Canaguier-Durand, Antoine ^{[1
,2
]}

Devaux, Eloise ^{[1
,2
]}

George, Jino ^{[1
,2
]}

Pang, Yantao ^{[1
,2
,3
]}

Hutchison, James A. ^{[1
,2
]}

Schwartz, Tal ^{[1
,2
]}

Genet, Cyriaque ^{[1
,2
]}

Wilhelms, Nadine ^{[1
,2
]}

Lehn, Jean-Marie ^{[1
,2
]}

Ebbesen, Thomas W. ^{[1
,2
]}

机构：

[1] ISIS, F-67000 Strasbourg, France

[2] icFRC, F-67000 Strasbourg, France

[3] Shandong Jianzhu Univ, Sch Sci, Jinan 250101, Shandong, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 40期

关键词：

strong coupling; thermodynamics; vacuum field; SINGLE QUANTUM-DOT; DYNAMICS;

D O I：

10.1002/anie.201301861

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The thermodynamics of strong coupling between molecules and the vacuum field is analyzed and the Gibbs free energy, the enthalpy, and entropy of the coupling process are determined for the first time. The thermodynamic parameters are a function of the Rabi splitting and the microscopic solvation. The results provide a new framework for understanding light-molecule strong coupling. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：10533 / 10536

页数：4

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