Characterization of a novel CuII/4,4'-bipyridine coordination polymer containing square grids

被引：0
|
作者：
Williams, PAM
Ferrer, EG
Baran, EJ
Piro, OE
Castellano, EE
机构：
[1] Natl Univ La Plata, Fac Ciencias Exactas, CEQUINOR, CONICET, RA-1900 La Plata, Argentina
[2] Natl Univ La Plata, Fac Ciencias Exactas, Inst IFLP, RA-1900 La Plata, Argentina
[3] Natl Univ La Plata, Fac Ciencias Exactas, Dept Fis, RA-1900 La Plata, Argentina
[4] Univ Sao Paulo, Inst Fis Sao Carlos, Sao Carlos, SP, Brazil
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2002年 / 628卷 / 9-10期
关键词：
copper; 4,4'-bipyridine; crystal structure; spectroscopic properties; thermal behaviour;
D O I：
10.1002/1521-3749(200209)628:9/10<2044::AID-ZAAC2044>3.0.CO;2-8
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
In an attempt to obtain new square and polymers we could prepare the copper(II) complex [Cu(4,4'-bipy)(2)(H2O2)(2)]-(sac)(2) . DMF (4,4'-bipy = 4,4'-bipyridine; sac = anion of saccharin; DMF = dimethylformamide). Its structure was determined by single crystal X-ray diffraction methods. It crystallizes in the orthorhombic space group Pcnb (a = 14.4994(2), b = 15,8128(3), c = 16.6850(2) A, Z = 4) and is a square grid polymer with the saccharinate anions sandwiched between the complex layers and the DMF molecules Filling the square holes. UV-vis, diffuse reflectance and IR spectra, room temperature magnetic susceptibility and the thermal behaviour were also investigated.
引用
收藏
页码：2044 / 2048
页数：5
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