Synthesis of boron-containing heterocyclic compounds

被引：11
作者：
Azev, Y
Slepukhina, I
Gabel, D
机构：
[1] Univ Bremen, Dept Chem, D-28334 Bremen, Germany
[2] Ural Sci Res Inst Technol Med Preparat, Ekaterinburg 620219, Russia
来源：
APPLIED RADIATION AND ISOTOPES | 2004年 / 61卷 / 05期
关键词：
heterocycles; triazines; carborane; dodecaborate;
D O I：
10.1016/j.apradiso.2004.05.002
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis of boron-containing 1,3,5-triazines and 1,2,4-triazines is described. Derivatives of 1,3,5-triazine containing the o-carborane cluster have been obtained by reacting the corresponding propargyl derivatives with B10H14. Derivatives of 1,2,4-triazine containing the B12H122- cluster have been obtained by nucleophilic substitution of ethylsulfone derivatives with B12H11SH2-. They have been isolated in their ring-protonated form. Reaction of RNH2-B8H11NH-R with stericly demanding heterocycles failed, either for steric or for solubility reasons. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1107 / 1110
页数：4
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