ReviewInverse coordination. Organic nitrogen heterocycles as coordination centers. A survey of molecular topologies and systematization. Part 1. Five-membered and smaller rings

被引：23

作者：

Haiduc, Ionel ^{[1
]}

机构：

[1] Univ Babes Bolyai, Fac Chim, Cluj Napoca, Romania

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2019年 / 72卷 / 13期

关键词：

Inverse coordination; metal complexes; molecular topology; nitrogen heterocycle; pyrazole; imidazole; triazole; tetrazole; pyrrole; oxadiazole; thiadiazole; diazaphosphole; diazirine; diazete; IMIDAZOLATE-BRIDGED COPPER; METAL-ION INTERACTIONS; X-RAY STRUCTURES; ISOMERIC HETERODINUCLEAR COMPLEXES; CONTAINING DINUCLEAR COMPLEXES; CAMBRIDGE STRUCTURAL DATABASE; TREN LIGAND-SYSTEM; CENTER-DOT CLO4; CRYSTAL-STRUCTURES; MACROCYCLIC LIGAND;

D O I：

10.1080/00958972.2019.1641702

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This review continues the previous articles (I. Haiduc, J. Coord. Chem., 71, 3139 (2018) and J. Coord. Chem., 72, 35 (2019)), which discussed the structures with nitrogen-donor species (atoms and molecules) acting as centers in inverse coordination complexes. i.e. metal compounds which display an arrangement of acceptor and donor sites opposite to that occurring in conventional coordination complexes. This review is Part 1 of a work which introduces the topology of inverse coordination complexes with organic nitrogen heterocycles, and presents a panorama of five-membered rings and covers pyrazole, imidazole, triazoles, tetrazole, pyrrole, oxadiazole, thiadiazole, azaphospholes, and smaller rings. [GRAPHICS] .

引用

页码：2127 / 2159

页数：33

共 278 条

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