cis-Bis(2,2′-bipyridine-4,4′-dicarboxylic acid-κ2N,N′)dichlororuthenium(II)monohydrate

被引：9

作者：

Fujihara, T

Kobayashi, A

Iwai, M

Nagasawa, A

机构：

[1] Saitama Univ, Fac Sci, Dept Chem, Sakura Ku, Saitama 3388570, Japan

[2] Kojima Chem Co Ltd, Sayama, Saitama 3501335, Japan

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2004年 / 60卷

关键词：

D O I：

10.1107/S1600536804017507

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The crystal structure of the title compound, [RuCl2(C12H8N2O4)(2)].H2O, which is a precursor of the dye for dyesensitized solar cells, is composed of a ruthenium(II) complex molecule containing 2,2'-bipyridine-4,4'-dicarboxylic acid (H(2)dcbpy) as a ligand and an uncoordinated water molecule. The overlapped arrangement and the separation of 3.34 (7) Angstrom suggest pi-pi stacking between parallel H(2)dcbpy ligands in neighboring complex molecules. A three-dimensional network is formed by intermolecular O-H...O and O-H...Cl hydrogen bonds and pi-pi stacking between neighboring complex molecules.

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页码：M1172 / M1174

页数：3

相关论文

共 10 条

[1]

*BRUK AXS INC, 2003, SAINT W2K NT VERS 5

[2] STRUCTURAL VARIATIONS INDUCED BY CHANGES IN OXIDATION-STATE AND THEIR ROLE IN ELECTRON-TRANSFER - CRYSTAL AND MOLECULAR-STRUCTURES OF CIS-[RU(BPY)2CL2].3.5H2O AND CIS-[RU(BPY)2CL2]CL.2H2O [J].

EGGLESTON, DS ;

GOLDSBY, KA ;

HODGSON, DJ ;

MEYER, TJ .

INORGANIC CHEMISTRY, 1985, 24 (26) :4573-4580

[3] Redox and photochemical behaviour of ruthenium(II) complexes with H2dcbpy ligand (H2dcbpy=2,2′-bipyridine-4,4′-dicarboxylic acid) [J].

Eskelinen, E ;

Luukkanen, S ;

Haukka, M ;

Ahlgrén, M ;

Pakkanen, TA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (16) :2745-2752

[4] ORTEP-3 for Windows - a version of ORTEP-III with a Graphical User Interface (GUI) [J].

Journal of Applied Crystallography, 1997, 30 (pt 5)

[5] Bis(tetraethylammonium) 2,2′-bipyridine-4,4′-dicarboxylate tetrahydrate [J].

Fujihara, T ;

Kobayashi, A ;

Nagasawa, A .

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2004, 60 :O353-O355

[6] Dye-sensitized solar cells [J].

Grätzel, M .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS, 2003, 4 (02) :145-153

[7] CIS-DIAQUABIS(2,2'-BIPYRIDYL-4,4'-DICARBOXYLATE)-RUTHENIUM(II) SENSITIZES WIDE BAND-GAP OXIDE SEMICONDUCTORS VERY EFFICIENTLY OVER A BROAD SPECTRAL RANGE IN THE VISIBLE [J].

LISKA, P ;

VLACHOPOULOS, N ;

NAZEERUDDIN, MK ;

COMTE, P ;

GRATZEL, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (11) :3686-3687

[8]

Sheldrick G.M., 1996, SADABS VERSION 2008

[9] Structure of organic/inorganic interface in assembled materials comprising molecular components.: Crystal structure of the sensitizer bis[(4,4′-carboxy-2,2′-bipyridine)(thiocyanato)]ruthenium(II) [J].

Shklover, V ;

Ovchinnikov, YE ;

Braginsky, LS ;

Zakeeruddin, SM ;

Gratzel, M .

CHEMISTRY OF MATERIALS, 1998, 10 (09) :2533-2541

[10] Crystal structures of Ru complex sensitizers of TiO2 anatase nanopowders [J].

Shklover, V ;

Haibach, T ;

Bolliger, B ;

Hochstrasser, M ;

Erbudak, M ;

Nissen, HU ;

Zakeeruddin, SM ;

Nazeeruddin, MK ;

Gratzel, M .

JOURNAL OF SOLID STATE CHEMISTRY, 1997, 132 (01) :60-72