Preparation of polyurea microcapsules containing ovalbumin

被引:44
作者
Hong, K [1 ]
Park, S [1 ]
机构
[1] Pusan Natl Univ, Dept Text Engn, Fac Appl Chem Engn, Pusan 609735, South Korea
关键词
polyurea microcapsule; ovalbumin; ethylene diamine; hexamethylene diamine; water-borne diamine;
D O I
10.1016/S0254-0584(99)00241-2
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Polyurea microcapsules containing a hydrophilic protein, ovalbumin were prepared by the reaction of toluene diisocyanate (TDI) with ethylene diamine (EDA), hexamethylene diamine (HDA), and water-borne diamine, and their characteristics were investigated for the wall structures, thermal properties, and morphologies. The microcapsules from EDA had the strongest intensity of -NH to -CH, showing production of the strongest wall membrane, while the intensity of microcapsules from HDA significantly decreased due to the relatively long methylene chain. From thermal analysis, it was concluded that polyurea microcapsules prepared in this study had thermal stability with endothermal peaks at 280 similar to 350 degrees C. (C) 2000 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:20 / 24
页数:5
相关论文
共 14 条
[1]   ON THE PHYSICAL CROSSLINKING OF AMINE-EXTENDED POLYURETHANE UREA ELASTOMERS - A CRYSTALLOGRAPHIC ANALYSIS OF BIS-UREA FROM DIPHENYL METHANE-4-ISOCYANATE AND 1,4-BUTANE DIAMINE [J].
BORN, L ;
HESPE, H .
COLLOID AND POLYMER SCIENCE, 1985, 263 (04) :335-341
[2]   POLYUREA SYNTHESIS AND PROPERTIES AS A FUNCTION OF HARD-SEGMENT CONTENT [J].
CHEN, ZS ;
YANG, WP ;
MACOSKO, CW .
RUBBER CHEMISTRY AND TECHNOLOGY, 1988, 61 (01) :86-99
[3]  
DOMINQUEZ RJG, 1984, P SPI 28 ANN TECHN M
[4]  
DOMINQUEZ RJG, 1987, P POL WORLD C, P213
[5]  
GAO T, 1994, J APPL POLYM SCI, V54, P1965
[6]  
HARIIS RF, 1995, POLYMER, V36, P4275
[7]   Melamine resin microcapsules containing fragrant oil: synthesis and characterization [J].
Hong, K ;
Park, S .
MATERIALS CHEMISTRY AND PHYSICS, 1999, 58 (02) :128-131
[8]  
HONG K, 1998, MAT RES B, V34, P963
[9]  
HONG K, 1998, IN PRESS REACTIVE FU
[10]  
ISHIHARA H, 1984, J MACROMOL SCI PHYS, VB22, P713, DOI 10.1080/00222348308215209