Room-Temperature C-H Bond Activation of Methane by Bare [P4O10]•+

被引：106

作者：

Dietl, Nicolas ^{[1
]}

Engeser, Marianne ^{[2
]}

Schwarz, Helmut ^{[1
]}

机构：

[1] Tech Univ Berlin, Inst Chem, D-10623 Berlin, Germany

[2] Univ Bonn, Kekule Inst Organ Chem & Biochem, D-5300 Bonn, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 26期

关键词：

C-H activation; cluster compounds; density functional calculations; gas-phase reactions; radicals; CATALYTIC-OXIDATION REACTIONS; METAL-OXIDE CLUSTERS; GAS-PHASE; REACTIVITY; CATIONS; OXYGEN; ETHYLENE; STATE; CH4; MOLYBDENUM;

D O I：

10.1002/anie.200901596

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

No need for a metal: A combination of mass spectrometry and computational studies (density functional theory and coupled-cluster methods) shows that [P4O10].+ is the first polynuclear nonmetal oxide cation that is capable of activating the C-H bond of methane at room temperature (see picture). This process represents a further example in the reactivity of oxygencentered radicals. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4861 / 4863

页数：3

共 50 条

[21] C-H BOND ACTIVATION AND FUNCTIONALIZATION OF METHANE UNDER MILD CONDITIONS
Zhang Liangfu
Ding Fujiang
Jin Hong
Jiang Qiongzhong
Yang Qi and Li Guangnian(Chengdu Institute of Organic Chemistry
Chinese Academy of Sciences
Chengdu
China)
分子催化, 1990, (S1) : 76 - 84
[22] Mechanism of the Ta+-mediated activation of the C-H bond in methane
Sandig, N
Koch, W
ORGANOMETALLICS, 1997, 16 (24) : 5244 - 5251
[23] PHOTOCHEMICAL C-H BOND ACTIVATION OF METHANE ON A PT(111) SURFACE
GRUZDKOV, YA
WATANABE, K
SAWABE, K
MATSUMOTO, Y
CHEMICAL PHYSICS LETTERS, 1994, 227 (03) : 243 - 247
[24] Thermodynamic Study: C-H Bond Activation of Methane with OsO+
Aynali, F.
Ciftcioglu, G. A. Altun
ACTA PHYSICA POLONICA A, 2015, 128 (2B) : B167 - B169
[25] MECHANISM OF ACTIVATION OF THE C-H BOND IN METHANE AND BENZENE IN THE PRESENCE OF VANADOCENE
SHESTAKOV, AF
ZHUK, SY
PAPOYAN, AT
GRIGORYAN, EA
KINETICS AND CATALYSIS, 1982, 23 (03) : 502 - 511
[26] Activation of the C-H bond of methane by intermediate Q of methane monoozygenase: A theoretical study
Gherman, BF
Dunietz, BD
Whittington, DA
Lippard, SJ
Friesner, RA
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (16) : 3836 - 3837
[27] NOVEL PLATINUM COMPLEXES ENABLE SELECTIVE C-H AND C-SI ACTIVATION OF TETRAMETHYLSILANE AT ROOM-TEMPERATURE
HOFMANN, P
HEISS, H
NEITELER, P
MULLER, G
LACHMANN, J
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (08): : 880 - 882
[28] Room-Temperature Rh(I)-Catalyzed P(III)-Directed C-H Bond Alkylation: Enhanced Reactivity through Ligand Acceleration
Zhang, Jian
Soule, Jean-Francois
ACS CATALYSIS, 2025,
[29] Recent Advances in Room-Temperature Direct C-H Arylation Methodologies
Yadav, Preeti
Velmurugan, Nivedha
Luscombe, Christine K.
SYNTHESIS-STUTTGART, 2023, 55 (01): : 1 - 26
[30] Room-temperature enantioselective C-H iodination via kinetic resolution
Chu, Ling
Xiao, Kai-Jiong
Yu, Jin-Quan
SCIENCE, 2014, 346 (6208) : 451 - 455

← 1 2 3 4 5 →