Room-Temperature C-H Bond Activation of Methane by Bare [P4O10]•+

被引：106

作者：

Dietl, Nicolas ^{[1
]}

Engeser, Marianne ^{[2
]}

Schwarz, Helmut ^{[1
]}

机构：

[1] Tech Univ Berlin, Inst Chem, D-10623 Berlin, Germany

[2] Univ Bonn, Kekule Inst Organ Chem & Biochem, D-5300 Bonn, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 26期

关键词：

C-H activation; cluster compounds; density functional calculations; gas-phase reactions; radicals; CATALYTIC-OXIDATION REACTIONS; METAL-OXIDE CLUSTERS; GAS-PHASE; REACTIVITY; CATIONS; OXYGEN; ETHYLENE; STATE; CH4; MOLYBDENUM;

D O I：

10.1002/anie.200901596

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

No need for a metal: A combination of mass spectrometry and computational studies (density functional theory and coupled-cluster methods) shows that [P4O10].+ is the first polynuclear nonmetal oxide cation that is capable of activating the C-H bond of methane at room temperature (see picture). This process represents a further example in the reactivity of oxygencentered radicals. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4861 / 4863

页数：3

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