Room-Temperature C-H Bond Activation of Methane by Bare [P4O10]•+

被引：106
|
作者：
Dietl, Nicolas [1 ]
Engeser, Marianne [2 ]
Schwarz, Helmut [1 ]
机构：
[1] Tech Univ Berlin, Inst Chem, D-10623 Berlin, Germany
[2] Univ Bonn, Kekule Inst Organ Chem & Biochem, D-5300 Bonn, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 26期
关键词：
C-H activation; cluster compounds; density functional calculations; gas-phase reactions; radicals; CATALYTIC-OXIDATION REACTIONS; METAL-OXIDE CLUSTERS; GAS-PHASE; REACTIVITY; CATIONS; OXYGEN; ETHYLENE; STATE; CH4; MOLYBDENUM;
D O I：
10.1002/anie.200901596
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
No need for a metal: A combination of mass spectrometry and computational studies (density functional theory and coupled-cluster methods) shows that [P4O10].+ is the first polynuclear nonmetal oxide cation that is capable of activating the C-H bond of methane at room temperature (see picture). This process represents a further example in the reactivity of oxygencentered radicals. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：4861 / 4863
页数：3
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