A Template-Free Method toward Urchin-Like Polyaniline Microspheres

被引：41

作者：

Wang, Junsheng ^{[1
]}

Wang, Jixiao ^{[1
]}

Wang, Zhi ^{[1
]}

Zhang, Fengbao ^{[1
]}

机构：

[1] Tianjin Univ, Sch Chem Engn & Technol, Chem Engn Res Ctr, State Key Lab Chem Engn, Tianjin 300072, Peoples R China

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2009年 / 30卷 / 08期

关键词：

conducting polymers; microspheres; microstructure; polyaniline; self-assembly; DOPED POLYANILINE; NANOFIBERS; NANOSTRUCTURES; NANOTUBES; ANILINE; ACIDS; POLYMERIZATION; MECHANISM; EVOLUTION; OXIDATION;

D O I：

10.1002/marc.200800726

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Urchin-like PANI microspheres with an average diameter of 5-10 mu m have been successfully prepared. Their surfaces consist of highly oriented nanofibers of approximate to 30 nm diameter and 1 mu m length. The solvent composition plays an important role in the formation process of urchin-like PANI microspheres. The structure of the products has been characterized by FT-IR, UV-vis, and XRD. To investigate the self-assembly of urchin-like PANI microspheres, the effect of polymerization time on the morphology of the products has been studied. The morphological evolution process indicates that the urchin-like microspheres originate from the self-assembly of nanoplates, which then grow into urchin-like microstructures with nanofibers on the surface.

引用

页码：604 / 608

页数：5

共 34 条

[11] Electrochemical performance of polyaniline nanofibres and polyaniline/multi-walled carbon nanotube composite as an electrode material for aqueous redox supercapacitors [J].