A new reaction of P4S10 and Lawesson's reagent;: a new method for the synthesis of dithieno[3,2-b;2′,3′-d]thiophenes

被引：52
作者：
Ertas, E
Ozturk, T [1 ]
机构：
[1] Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey
[2] TUBITAK, Marmara Res Ctr, Dept Chem, Gebze, Turkey
来源：
TETRAHEDRON LETTERS | 2004年 / 45卷 / 17期
关键词：
phosphorus pentasulfide; Lawesson's reagent; (LR); dithienothiophene; DTT;
D O I：
10.1016/j.tetlet.2004.03.023
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new reaction of P4S10 and Lawesson's reagent for the synthesis of used thiophenes has been uncovered. It has given easy access to the synthesis of, derivatives of the technologically important heterocycle dithieno[3,2-h:2'.3'-d]thiophene, DTT. Electrochemical polymerization of one of the derivatives, has been demonstrated. (C) 2004 Published by Elsevier Ltd.
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收藏
页码：3405 / 3407
页数：3
相关论文
共 23 条
[1]   A convenient and improved synthesis of dithieno[3,2-b:2′,3′-d]thiophene [J].
Allared, F ;
Hellberg, J ;
Remonen, T .
TETRAHEDRON LETTERS, 2002, 43 (08) :1553-1554
[2]   Rigid-core oligothiophene-S,S-dioxides with high photoluminescence efficiencies both in solution and in the solid state [J].
Barbarella, G ;
Favaretto, L ;
Sotgiu, G ;
Antolini, L ;
Gigli, G ;
Cingolani, R ;
Bongini, A .
CHEMISTRY OF MATERIALS, 2001, 13 (11) :4112-4122
[3]  
BERTINELLI F, 1984, MOL CRYST LIQ CRYST, V109, P289, DOI 10.1080/00268948408078714
[4]  
De Jong F, 1971, J ORG CHEM, V36, P1645
[5]  
DIMARCO P, 1985, MOL CRYST LIQ CRYST, V118, P241, DOI 10.1080/00268948508076217
[6]   An important application of the 1,8-diketone ring formation reaction:: a concise synthesis of 5,6-diphenyl[1,3]dithiolo[4,5-b][1,4]dithiine-2-thione and its coupling product [J].
Ertas, E ;
Ozturk, T .
CHEMICAL COMMUNICATIONS, 2000, (20) :2039-2040
[7]   Improved synthesis of dithieno[3,2-b:2′,3′-d] thiophene (DTT) and derivatives for cross coupling [J].
Frey, J ;
Bond, AD ;
Holmes, AB .
CHEMICAL COMMUNICATIONS, 2002, (20) :2424-2425
[8]   Photochemical polymerization of dithienothiophenes [J].
Fujitsuka, M ;
Sato, T ;
Watanabe, A ;
Ito, O ;
Shimidzu, T .
CHEMISTRY LETTERS, 1996, (04) :285-286
[9]   THE X-RAY CRYSTAL-STRUCTURE OF A CHARGE-TRANSFER COMPLEX DERIVED FROM A NONPLANAR, BULKY, AND CONFORMATIONALLY FLEXIBLE DONOR COMPOUND [J].
HAYASHI, N ;
MAZAKI, Y ;
KOBAYASHI, K .
CHEMISTRY LETTERS, 1992, (09) :1689-1692
[10]   Nonlinear optical chromophores containing dithienothiophene as a new type of electron relay [J].
Kim, OK ;
Fort, A ;
Barzoukas, M ;
Blanchard-Desce, M ;
Lehn, JM .
JOURNAL OF MATERIALS CHEMISTRY, 1999, 9 (09) :2227-2232
123