Electrochemical supercapacitor behavior of nanoparticulate rutile-type Ru1-xVxO2

被引：33

作者：

Yokoshima, Katsunori ^{[1
]}

Shibutani, Takuyoshi ^{[1
]}

Hirota, Masashi ^{[1
]}

Sugimoto, Wataru ^{[1
]}

Murakami, Yasushi ^{[1
]}

Takasu, Yoshio ^{[1
]}

机构：

[1] Shinshu Univ, Fac Text Sci & Technol, Dept Fine Mat Engn, Ueda, Nagano 3868567, Japan

来源：

JOURNAL OF POWER SOURCES | 2006年 / 160卷 / 02期

关键词：

electrochemical capacitor; supercapacitor; rutile; ruthenium oxide; cyclic voltammetry;

D O I：

10.1016/j.jpowsour.2006.02.053

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Rutile-type Ru1-xVxO2 nanoparticles possessing high surface area were prepared by a polymerizable-complex method and its electrochemical supercapacitor behavior was studied. X-ray diffractometry, energy-dispersive X-ray analysis, and N-2 adsorption/desorption measurements were used to characterize the structure of the products. The electrochemical supercapacitor behavior of thick and thin films was studied by cyclic voltammetry in various acidic, neutral, and alkaline electrolytes. Ru1-xVxO2 exhibited extremely enhanced supercapacitive properties compared to pure RuO2. The highest surface redox activity was achieved with an acidic electrolyte. Ru1-xVxO2 showed negligible surface redox activity in neutral electrolytes. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：1480 / 1486

页数：7

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