Nitrogen-Doped Mesoporous Carbon Material (N-GMC) as a Highly Efficient Catalyst for Carbon Dioxide Fixation Reaction with Epoxides under metal-free condition

被引：30
作者：
Molla, Rostam Ali [1 ]
Iqubal, Asif [2 ]
Ghosh, Kajari [1 ]
Islam, Manirul [1 ]
机构：
[1] Univ Kalyani, Dept Chem, Nadia 741235, W Bengal, India
[2] IIT Roorkee, Dept Chem, Roorkee 247667, Uttarakhand, India
来源：
CHEMISTRYSELECT | 2016年 / 1卷 / 12期
关键词：
Nitrogen-doped Carbon; mesoporous carbon; CO2; fixation; cyclic carbonate; OXYGEN REDUCTION REACTION; PROTIC IONIC LIQUIDS; CYCLIC CARBONATE; CHEMICAL FIXATION; HETEROGENEOUS CATALYSTS; HYDROTHERMAL CARBON; ORGANIC POLYMERS; MILD CONDITIONS; CO2; CAPTURE; CONVERSION;
D O I：
10.1002/slct.201600346
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A soft template (Brij 35) controlled nitrogen-doped mesoporous carbon material (N-GMC) was prepared from glucose as a carbon source and melamine as a nitrogen source. The synthesized material was characterized by XRD, SEM, HRTEM, XPS, and Raman spectroscopy and nitrogen adsorption and desorption isotherms. Nitrogen enriches carbon material with high surface area and porous channel showed high CO2 fixation reaction at low temperature and ambient pressure. Excellent catalytic activity and reusability showed towards cyclic carbonate synthesis from various epoxides under metal free condition.
引用
收藏
页码：3100 / 3107
页数：8
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