Nitrogen-Doped Mesoporous Carbon Material (N-GMC) as a Highly Efficient Catalyst for Carbon Dioxide Fixation Reaction with Epoxides under metal-free condition

被引：32

作者：

Molla, Rostam Ali ^{[1
]}

Iqubal, Asif ^{[2
]}

Ghosh, Kajari ^{[1
]}

Islam, Manirul ^{[1
]}

机构：

[1] Univ Kalyani, Dept Chem, Nadia 741235, W Bengal, India

[2] IIT Roorkee, Dept Chem, Roorkee 247667, Uttarakhand, India

来源：

CHEMISTRYSELECT | 2016年 / 1卷 / 12期

关键词：

Nitrogen-doped Carbon; mesoporous carbon; CO2; fixation; cyclic carbonate; OXYGEN REDUCTION REACTION; PROTIC IONIC LIQUIDS; CYCLIC CARBONATE; CHEMICAL FIXATION; HETEROGENEOUS CATALYSTS; HYDROTHERMAL CARBON; ORGANIC POLYMERS; MILD CONDITIONS; CO2; CAPTURE; CONVERSION;

D O I：

10.1002/slct.201600346

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A soft template (Brij 35) controlled nitrogen-doped mesoporous carbon material (N-GMC) was prepared from glucose as a carbon source and melamine as a nitrogen source. The synthesized material was characterized by XRD, SEM, HRTEM, XPS, and Raman spectroscopy and nitrogen adsorption and desorption isotherms. Nitrogen enriches carbon material with high surface area and porous channel showed high CO2 fixation reaction at low temperature and ambient pressure. Excellent catalytic activity and reusability showed towards cyclic carbonate synthesis from various epoxides under metal free condition.

引用

页码：3100 / 3107

页数：8

共 71 条

[1]

Allen S. D., ACS S SERIES, V921, P116

[2]

[Anonymous], 2009, ANGEW CHEM-GER EDIT

[3]

Aresta M., 2010, CARBON DIOXIDE CHEM

[4] Utilisation of CO2 as a chemical feedstock:: opportunities and challenges [J].

Aresta, Michele ;

Dibenedetto, Angela .

DALTON TRANSACTIONS, 2007, (28) :2975-2992

[5] Dual-porous metal organic framework for room temperature CO2 fixation via cyclic carbonate synthesis [J].

Babu, Robin ;

Kathalikkattil, Amal Cherian ;

Roshan, Roshith ;

Tharun, Jose ;

Kim, Dong-Woo ;

Park, Dae-Won .

GREEN CHEMISTRY, 2016, 18 (01) :232-242

[6] Cycloaddition of CO2 to epoxides over both homogeneous and silica-supported guanidine catalysts [J].

Barbarini, A ;

Maggi, R ;

Mazzacani, A ;

Mori, G ;

Sartori, G ;

Sartorio, R .

TETRAHEDRON LETTERS, 2003, 44 (14) :2931-2934

[7] Highly integrated CO2 capture and conversion: direct synthesis of cyclic carbonates from industrial flue gas [J].

Barthel, Alexander ;

Saih, Youssef ;

Gimenez, Michel ;

Pelletier, Jeremie D. A. ;

Kuehn, F. E. ;

D'Elia, Valerio ;

Basset, Jean-Marie .

GREEN CHEMISTRY, 2016, 18 (10) :3116-3123

[8] Zn(II) assisted synthesis of porous salen as an efficient heterogeneous scaffold for capture and conversion of CO2 [J].

Bhunia, Subhajit ;

Molla, Rostam Ali ;

Kumari, Vandana ;

Islamb, Sk. Manirul ;

Bhaumik, Asim .

CHEMICAL COMMUNICATIONS, 2015, 51 (86) :15732-15735

[9] Cyclic carbonate formation from carbon dioxide and oxiranes in tetrabutylammonium halides as solvents and catalysts [J].

Caló, V ;

Nacci, A ;

Monopoli, A ;

Fanizzi, A .

ORGANIC LETTERS, 2002, 4 (15) :2561-2563

[10] Preparation of Nitrogen-Doped Carbon Spheres by Injecting Pyrolysis of Pyridine [J].

Cao, Bin ;

Liu, Huan ;

Xing, Zhou ;

Lei, Yaofei ;

Song, Huaihe ;

Chen, Xiaohong ;

Zhou, Jisheng ;

Ma, Zhaokun .

ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2015, 3 (08) :1786-1793

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