Photoinitiated rearrangements of 3-phenylnorbornadiene with conjugated substituents in 2-position

被引：11

作者：

Chernoivanov, VA

Dubonosov, AD

Bren, VA

Minkin, VI

Suslov, AN

Borodkin, GS

机构：

[1] Inst. of Phys. and Organic Chemistry, Rostov State University, Rostov on Don, 344090

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1997年 / 297卷

关键词：

D O I：

10.1080/10587259708036128

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

A series of novel 3-phenylnorbomadienes with conjugated substituents in 2-position (carbaldimine, carbaldoxime, amide, aroylvinyl and heterocyclic groups) have been synthesized. All the compounds obtained absorb in the 310-420 nm spectral region and under UV-Vis-irradiation form corresponding quadricyclanes with quantum yields in the range of 0.1-0.7. The back reaction proceeds almost quantitative yield under homogeneous and heterogeneous catalysis or on heating.

引用

页码：239 / 245

页数：7