{Bis[2-(diphenylphosphino)phenyl] ether-κ2P:P′}(dimethyl 2,2′-biphenyl-4,4′-dicarboxylate-κ2N:N′)copper(I) hexafluoridophosphate acetonitrile solvate

被引：1

作者：

Yu, Ai-Guo ^{[1
]}

Zhang, Ming ^{[1
]}

Yang, Guang-Di ^{[1
]}

Ye, Ling ^{[1
]}

Ma, Yu-Guang ^{[1
]}

机构：

[1] Jilin Univ, Coll Chem, State Key Lab Supramol Struct & Mat, Changchun 130012, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷

基金：

美国国家科学基金会;

关键词：

D O I：

10.1107/S1600536809024982

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, [Cu(C14H12N2O4)(C36H28OP2)] PF6 center dot-CH3CN, the Cu(I) ion is coordinated by two N atoms from the dimethyl 2,2'-biphenyl-4,4'-dicarboxylate ligand and two P atoms from the bis[2-(diphenylphosphino)phenyl] ether ligand in a distorted tetrahedral environment. In the cation, the short distance of 3.870 (4) angstrom between the centroids of the benzene and phenyl rings suggests the existence of intramolecular pi-pi interactions.

引用

页码：M875 / U504

页数：13

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