Preparation of a new nanocomposite of Al0.33Mg0.67(OH)2(C12H25SO4)0.33 and poly(ethylene oxide)

被引:60
作者
Bubniak, GA
Schreiner, WH
Mattoso, N
Wypych, F
机构
[1] Univ Fed Parana, CEPESQ, Ctr Pesquisas Quim, Dept Quim, BR-81531900 Curitiba, Parana, Brazil
[2] Univ Fed Parana, Dept Fis, BR-81531900 Curitiba, Parana, Brazil
关键词
D O I
10.1021/la011748d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new nanocomposite was synthesized by reacting the layered double hydroxide Al0.33Mg0.67(OH)(2)(C12H25SO4)(0.33).0.64H(2)O with poly(ethylene oxide). The composite was characterized with X-ray powder diffraction, thermal analysis (simultaneous thermogravimetric analysis/differential scanning calorimetry), Fourier transform infrared spectroscopy, photoelectron spectroscopy, and electron diffraction. The. nanocomposite has the layered structure of the double hydroxide simultaneously intercalated with dodecyl sulfate anions and poly(ethylene oxide) molecules. The characterization indicates a nanocomposite with a well-ordered structure.
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页码:5967 / 5970
页数:4
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