Synthesis and Properties of Novel Phenylenediamine Gemini Surfactants

被引:8
|
作者
Xu, Hujun [1 ]
Wang, Chen [1 ]
Lin, Liangliang [1 ]
Xu, Jin [2 ]
机构
[1] Jiangnan Univ, Sch Chem & Mat Engn, Wuxi 214122, Jiangsu, Peoples R China
[2] Guangzhou Chaohui Biol Technol Co Ltd, Guangzhou 510730, Guangdong, Peoples R China
关键词
Gemini surfactants; Surface activity; Synthesis; Antimicrobial properties; Phenylenediamine; ALKANEDIYL-ALPHA; OMEGA-BIS(DIMETHYLALKYLAMMONIUM BROMIDE) SURFACTANTS; ACTIVE PROPERTIES; CATIONIC SURFACTANTS; MICELLIZATION; AGGREGATION; ADSORPTION;
D O I
10.1002/jsde.12292
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
In the present work, a two-step method was adopted to synthesize a series of novel Gemini surfactants using N,N-dimethylalkyl amines (alkyl length = C-12, C-16 and C-18), epichlorohydrin, and n-phenyllenediamine as starting materials. The products were characterized using mass spectroscopy (MS) and nuclear magnetic resonance spectroscopy (H-1 NMR). Systematic experiments were conducted to evaluate their surface activity, foaming properties, and antibacterial performance. Results showed the critical micelle concentrations (CMC) of the C-12-based, C-16-based, and C-18-based phenylenediamine surfactants were 3.295 x 10(-3), 2.532 x 10(-4), and 3.140 x 10(-4) mol L-1 at 298 K, respectively, with corresponding surface tension (gamma(cmc)) values of 28.24, 31.95, and 35.06 mN m(-1) under the same conditions. The Gemini surfactants showed not only good surface activity and foaming properties, but also demonstrated good antimicrobial performance against Gram-positive and Gram-negative bacteria and fungi.
引用
收藏
页码:683 / 690
页数:8
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