Enabling future nanomanufacturing through block copolymer self-assembly: A review

被引:161
作者
Cummins, Cian [1 ,2 ]
Lundy, Ross [3 ,4 ]
Walsh, James J. [5 ,6 ]
Ponsinet, Virginie [2 ]
Fleury, Guillaume [1 ]
Morris, Michael A. [3 ,4 ]
机构
[1] Univ Bordeaux, CNRS, Bordeaux INP, LCPO,UMR 5629, F-33600 Pessac, France
[2] Univ Bordeaux, CNRS, Ctr Rech Paul Pascal CRPP, UMR 5031, F-33600 Pessac, France
[3] Trinity Coll Dublin, AMBER Res Ctr, Dublin, Ireland
[4] Trinity Coll Dublin, Sch Chem, Dublin, Ireland
[5] Dublin City Univ, Sch Chem Sci, Dublin 9, Ireland
[6] Dublin City Univ, Natl Ctr Sensor Res, Dublin 9, Ireland
基金
爱尔兰科学基金会;
关键词
Block copolymers; Self-assembly; Bottom-up fabrication; Nanomanufacturing; Nanodevices; CHARGE-MOSAIC MEMBRANE; PHOTONIC CRYSTALS; DRUG-DELIVERY; THIN-FILMS; SOL-GEL; PHOTOCATALYTIC PERFORMANCE; NANOPOROUS POLYSTYRENE; MICROPHASE SEPARATION; DIBLOCK COPOLYMERS; HYDROGEN EVOLUTION;
D O I
10.1016/j.nantod.2020.100936
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Self-assembly approaches, e.g. colloidal, emulsion and polymer phase separation, provide scientists with an exotic yet direct platform to access technologically desired nanostructures at competitive costs. In particular, soft nanomaterial systems such as block copolymer (BCP) materials present a powerful means to tailor templates and spatially controlled systems that are amenable to large scale manufacturing practices. BCP nanoarchitectures in bulk, solution and thin film form can act as structural motifs to template foreign materials and pave the way towards important applications across industry and society. While extensive literature and research efforts exist on electronic device uses using BCPs, we look at nascent applications outside the integrated circuit realm. Recent reports are discussed including for example; light-harvesting (energy - section 2), metasurfaces (photonics - section 3), nanofiltration membranes (environmental - section 4) and antibacterial activity (biological - section 5). We endeavour to illustrate the window of opportunity presented through BCP self-assembly for nanomanufacturing. We believe the highlights discussed will aid in directing new research initiatives and facilitate the large-scale integration of BCP materials with broad societal impact. (C) 2020 Elsevier Ltd. All rights reserved.
引用
收藏
页数:32
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