Convenient and efficient reduction of 1,1′-binaphthyls to H8-1,1′-binaphthyl derivatives with Pd and Ru catalysts on solid support

被引：55

作者：

Korostylev, A

Tararov, VI

Fischer, C

Monsees, A

Börner, A

机构：

[1] Univ Rostock, Leibniz Inst Organ Katalyse, D-18055 Rostock, Germany

[2] Degussa AG, Projekthaus Katalyse, D-65926 Frankfurt, Germany

[3] Univ Rostock, Fachbereich Chem, D-18059 Rostock, Germany

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2004年 / 69卷 / 09期

关键词：

D O I：

10.1021/jo0497609

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Hydrogenation of chiral 2,2'-functionalized 1,1'-binaphthyls with Pd and Ru solid-supported metal catalysts was found to be a clean and convenient pathway to 5,5',6,6',7,7',8,8'-octahydro-1,1'-dinaphthyl derivatives. In most cases no racemization was observed in the course of the reaction.

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页码：3220 / 3221

页数：2

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