Synthesis and crystal structure of tetraethyl-bis(μ-2(2-pyridyl)ethoxyl-O)-diindium(III)

被引：0

作者：

Hu, JZ ^{[1
]}

Yang, M ^{[1
]}

Wu, XS ^{[1
]}

Pan, Y ^{[1
]}

Liu, YJ ^{[1
]}

Sun, XZ ^{[1
]}

机构：

[1] Nanjing Univ, Dept Chem, Natl MO Precursor R&D Ctr, Nanjing 210093, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 1999年 / 15卷 / 03期

关键词：

1-(2-pyridyl)-2-propanol; triethylindium; indium complex; crystal structure;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new dimeric tetraethyl-bis(mu-2-(2-pyridyl)ethoxy-O)-diindium (III) complex (C(12)H(20)NOln)(2) was synthesized from the reaction of 1-(2-pyridyl)-2-propanol with triethylindium, Crystal structure of the complex was determined by X-ray analysis, The compound is central symmetric. The crystal data are as follow: Monoclinic, P2(1/n), a = 10. 609(2) Angstrom, b = 10. 680(3) Angstrom, c = 12. 012(8) Angstrom, beta = 95. 57(5)degrees, V = 1354. 5(10) Angstrom(3), Z = 1, F(000) = 624, Dc = 1. 516 g/cm(3), mu = 1. 722 mm(-1), Indium is five coordinate, In-O bond distances are 2. 131 Angstrom and 2. 248 Angstrom. angle InOIn = 106. 66 degrees, angle OlnO =73. 34 degrees.

引用

页码：347 / 350

页数：4

共 12 条

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