Aqueous-phase selective hydrogenation of phenol to cyclohexanone over soluble Pd nanoparticles

被引：91

作者：

Zhu, Jing-Fang ^{[1
,3
]}

Tao, Guo-Hong ^{[1
]}

Liu, Hang-Yu ^{[1
]}

He, Ling ^{[1
]}

Sun, Qian-Hui ^{[2
]}

Liu, Hai-Chao ^{[2
]}

机构：

[1] Sichuan Univ, Coll Chem, Chengdu 610064, Peoples R China

[2] Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China

[3] Kunming Sino Platinum Met Catalyst Co Ltd, Kunming 650101, Peoples R China

来源：

GREEN CHEMISTRY | 2014年 / 16卷 / 05期

关键词：

SUPPORTED PALLADIUM CATALYSTS; RUTHENIUM NANOCLUSTER CATALYST; SUPERCRITICAL CARBON-DIOXIDE; IONIC LIQUIDS; OXIDATION; GREEN; DERIVATIVES; PRECURSORS; COPPER; HOLLOW;

D O I：

10.1039/c3gc42408a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The water-soluble metal nanoparticles (NPs) stabilizedby poly(N-vinyl-2-pyrrolidone) (PVP) were prepared and examined as catalysts for the one-step selective hydrogenation of phenol to cyclohexanone in water. More than 99% conversion of phenol and selectivity to cyclohexanone was obtained at 90 degrees C and 1 atm H-2 for 16 h over "soluble"Pd NPs that were reduced by NaBH4 and stabilized by PVP. These Pd NPs were stable, and no leaching or aggregation was detected after five successive runs, showing their advantage for catalyzing the efficient synthesis of cyclohexanone via the one-step selective hydrogenation of phenol under mild conditions.

引用

页码：2664 / 2669

页数：6

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