Synthesis and crystal structure of a sandwiched trinuclear complex [Tl2(18-crown-6)2Pt(CN)4]•2H2O

被引：0
作者：
Liu Feng-Hui
Chen Wan-Zhi [1 ]
Wang Da-Qi
机构：
[1] Zhejiang Univ, Dept Chem, Hangzhou 310028, Peoples R China
[2] Liaocheng Univ, Dept Chem & Chem Engn, Liaocheng 252059, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2006年 / 25卷 / 06期
关键词：
platinum; thallium; cyanide; 18-crown-6; crystal structure;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The trinuclear complex bis(18-crown-6)thallium tetracyanoplatinate [Tl-2(18-crown-6)(2)Pt(CN)(4)]center dot 2H(2)O was prepared and its structure was determined by X-ray diffraction analysis. The compound (C28H52N4O14PtTl2, M-r = 1272.57) crystallizes in monoclinic, space group P2(1)In with a = 10.5180(10), b = 8.6162(8), c = 21.118(2) angstrom, beta = 92.577(2)degrees, V = 1911.9(3) angstrom(3), Z = 2, D-c = 2.211 g/cm(3), F(000) 1200, mu = 12.123 mm(-1), R = 0.0181 and wR = 0.0427. The linearly arranged three metals are sandwiched by two 18-crown-6 molecules.
引用
收藏
页码：677 / 680
页数：4
相关论文
共 14 条
[1]   Four thallium(I) ions sandwiched by two tetraalkynylplatinate ([Pt(C≡CR)4]2-) fragments:: Synthesis and luminescent behavior of Pt2Tl4 species [J].
Berenguer, JR ;
Forniés, J ;
Gómez, J ;
Lalinde, E ;
Moreno, MT .
ORGANOMETALLICS, 2001, 20 (23) :4847-4851
[2]   STRUCTURAL STUDIES OF PRECURSOR AND PARTIALLY OXIDIZED CONDUCTING COMPLEXES .20. REDUCTION IN PLATINUM-CHAIN DIMERIZATION IN RUBIDIUM TETRACYANOPLATINATE CHLORIDE (2-1-0.3) TRIHYDRATE, RB2[PT(CN)4]CL0.3.3.0H2O, AT 110-K AS REVEALED BY A NEUTRON-DIFFRACTION STUDY [J].
BROWN, RK ;
WILLIAMS, JM .
INORGANIC CHEMISTRY, 1979, 18 (07) :1922-1925
[3]   Synthesis and characterization of Pt(CN-p-(C2H5)C6H4)2(CN)2, a crystalline vapoluminescent compound that detects vapor-phase aromatic hydrocarbons [J].
Buss, CE ;
Mann, KR .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (06) :1031-1039
[4]   Mixed-metal metal locryptands. Short metal-metal separations strengthened by a dipolar interaction [J].
Catalano, VJ ;
Malwitz, MA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (21) :6560-6561
[5]   Unsupported Pt(0)-Tl(I) bonds in the simple [Pt(PPh2Py)3Tl]+ complexes [J].
Catalano, VJ ;
Bennett, BL ;
Muratidis, S ;
Noll, BC .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (01) :173-174
[6]   Synthesis and electrical and optical properties of [PtTl2-xLix(C6F5)2(CCPh)2] (x=0, 1) [J].
Charmant, JPH ;
Forniés, J ;
Gómez, J ;
Lalinde, E ;
Merino, RI ;
Moreno, MT ;
Orpen, AG .
ORGANOMETALLICS, 2003, 22 (04) :652-656
[7]   ''Vapochromic'' compounds as environmental sensors .2. Synthesis and near-infrared and infrared spectroscopy studies of [Pt(arylisocyanide)(4)][Pt(CN)(4)] upon exposure to volatile organic compound vapors [J].
Daws, CA ;
Exstrom, CL ;
Sowa, JR ;
Mann, KR .
CHEMISTRY OF MATERIALS, 1997, 9 (01) :363-368
[8]   Infrared spectroscopy studies of platinum salts containing tetracyanoplatinate(II). Evidence for strong hydrogen-bonding interactions in "vapochromic" environmental sensor materials [J].
Exstrom, CL ;
Pomije, MK ;
Mann, KR .
CHEMISTRY OF MATERIALS, 1998, 10 (03) :942-945
[9]   NOVEL QUASI-ONE-DIMENSIONAL ZIG-ZAG PLATINUM ATOM CHAIN IN K175PT(CN)4-1.5H2O - NEUTRON-DIFFRACTION STUDY [J].
KEEFER, KD ;
WASHECHECK, DM ;
ENRIGHT, NP ;
WILLIAMS, JM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (01) :233-234
[10]   TL2PT(CN)4 - A NONCOLUMNAR, LUMINESCENT FORM OF PT(CN)42- CONTAINING PT-TL BONDS [J].
NAGLE, JK ;
BALCH, AL ;
OLMSTEAD, MM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (01) :319-321
12