A Facile Fabrication of Poly-ethionine Film on Glassy Carbon Electrode for Simultaneous and Sensitive Detection of Dopamine and Paracetamol

被引:17
作者
Kannan, Ayyadurai [1 ]
Manojkumar, Seenivasan [1 ,2 ]
Radhakrishnan, Sivaprakasam [3 ]
机构
[1] Vivekananda Coll, Postgrad & Res Dept Chem, Madurai 625234, Tamil Nadu, India
[2] Ming Chi Univ Technol, Battery Res Ctr Green Energy, New Taipei 243, Taiwan
[3] CSIR Cent Electrochem Res Inst, Electrod & Electrocatalysis Div, Karaikkudi 630003, Tamil Nadu, India
关键词
Electrochemical polymerization; ethionine; electrochemical sensor; dopamine; paracetamol;
D O I
10.1002/elan.202060451
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
An electrochemical sensor based on poly-ethionine (Poly-ET) film modified glassy carbon electrode was developed for sensitive and simultaneous sensing of dopamine (DA) and paracetamol (PA). The electropolymerization of ethionine monomer was carried out to modify the electrode. The modified electrode was characterized by using scanning electron microscopy, cyclic voltammetry and electrochemical impedance spectroscopy. The Poly-ET/GCE exhibited excellent electrocatalysis towards the sensing of DA and PA. Poly-ET/GCE showed a linear increase of current response with increase concentration of DA and PA ranging from 0.1 mu M-60 mu M and 0.1 mu M-180 mu M, respectively. The LODs were found to be 7 nM and 18 nM (S/N=3) for DA and PA, respectively. This electrochemical sensor was successfully utilized for the detection of DA and PA in pharmaceutical samples.
引用
收藏
页码:1175 / 1184
页数:10
相关论文
共 46 条
[1]   Palladium nanoclusters-coated polyfuran as a novel sensor for catecholamine neurotransmitters and paracetamol [J].
Atta, Nada F. ;
El-Kady, Maher F. ;
Galal, Ahmed .
SENSORS AND ACTUATORS B-CHEMICAL, 2009, 141 (02) :566-574
[2]   A sensitive simultaneous determination of dopamine, acetaminophen and indomethacin on a glassy carbon electrode coated with a new composite of MCM-41 molecular sieve/nickel hydroxide nanoparticles/multiwalled carbon nanotubes [J].
Babaei, Ali ;
Yousefi, Akbar ;
Afrasiabi, Mohammad ;
Shabanian, Meisam .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2015, 740 :28-36
[3]   Electrochemical sensor based on reduced graphene oxide/carbon black/chitosan composite for the simultaneous determination of dopamine and paracetamol concentrations in urine samples [J].
Baccarin, Marina ;
Santos, Fabricio A. ;
Vicentini, Fernando C. ;
Zucolotto, Valtencir ;
Janegitz, Bruno C. ;
Fatibello-Filho, Orlando .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2017, 799 :436-443
[4]   Electrochemical sensors and biosensors based on redox polymer/carbon nanotube modified electrodes: A review [J].
Barsan, Madalina M. ;
Ghica, M. Emilia ;
Brett, Christopher M. A. .
ANALYTICA CHIMICA ACTA, 2015, 881 :1-23
[5]   Sol-gel thin-film based mesoporous silica and carbon nanotubes for the determination of dopamine, uric acid and paracetamol in urine [J].
Canevari, Thiago C. ;
Raymundo-Pereira, Paulo A. ;
Landers, Richard ;
Benvenutti, Edilson V. ;
Machado, Sergio A. S. .
TALANTA, 2013, 116 :726-735
[6]   Investigation on the downregulation of dopamine by acetaminophen administration based on their simultaneous determination in urine [J].
Chandra, Pranjal ;
Son, Nguyen X. ;
Noh, Hui-Bog ;
Goyal, Rajendra N. ;
Shim, Yoon-Bo .
BIOSENSORS & BIOELECTRONICS, 2013, 39 (01) :139-144
[7]   A comparative study of the electrochemical characteristics and simultaneous determination of dopamine, acetaminophen, and aspirin at a ruthenium oxide nanoparticles modified glassy carbon electrode versus a bare one [J].
Chatraei, Fatemeh ;
Zare, Hamid R. .
ANALYTICAL METHODS, 2012, 4 (09) :2940-2947
[8]   Highly sensitive and selective determination of pyrazinamide at poly-L-methionine/reduced graphene oxide modified electrode by differential pulse voltammetry in human blood plasma and urine samples [J].
Cheemalapati, Srikanth ;
Devadas, Balamurugan ;
Chen, Shen-Ming .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2014, 418 :132-139
[9]   Simultaneous electrochemical determination of dopamine and paracetamol on multiwalled carbon nanotubes/graphene oxide nanocomposite-modified glassy carbon electrode [J].
Cheemalapati, Srikanth ;
Palanisamy, Selvakumar ;
Mani, Veerappan ;
Chen, Shen-Ming .
TALANTA, 2013, 117 :297-304
[10]   Simultaneous electrochemical determination of dopamine and ascorbic acid using poly (L-serine) modified carbon paste electrode [J].
Chitravathi, S. ;
Swamy, B. E. Kumara ;
Mamatha, G. P. ;
Sherigara, B. S. .
JOURNAL OF MOLECULAR LIQUIDS, 2011, 160 (03) :193-199