ZnO nanorods inserted graphene sheets with improved supercapacitive performance

被引:33
作者
Qin, Z. [1 ]
Li, Z. J. [2 ]
Yun, G. Q. [2 ]
Shi, K. [2 ]
Li, K. [3 ]
Yang, B. C. [3 ]
机构
[1] North China Univ Water Resources & Elect Power, Coll Math & Informat Sci, Zhengzhou 450011, Peoples R China
[2] Zhengzhou Univ Light Ind, Sch Phys & Elect Engn, Zhengzhou 450002, Peoples R China
[3] Huanghe Univ Sci & Technol, Inst Nano Funct Mat, Zhengzhou 450006, Peoples R China
基金
中国国家自然科学基金;
关键词
Zinc oxide nanorods; Graphene nanosheets; Electrochemical performance; SOLID-STATE SUPERCAPACITORS; ELECTROCHEMICAL CHARACTERIZATION; ARRAYS; COMPOSITE; STORAGE; PAPER; OXIDE;
D O I
10.1016/j.apsusc.2013.12.007
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this paper, we demonstrate a facile one-pot approach for the synthesis of reduced graphene oxide-ZnO (Gr-ZnO) hybrids. Structural analysis revealed a homogeneous distribution of ZnO nanorods are inserted in graphene nanosheets, formed a sandwiched architecture. The Gr-ZnO material demonstrates superior electrochemical performance with high specific capacitance (140 F g(-1) even at the scan rate of 500 mV s(-1)) and long-term cycle stability (94% capacitance retention over 2000 cycles). The improved supercapacitance property of these materials could be ascribed to the increased the specific surface of graphene sheets by ZnO nanorods inserted. These results demonstrate the potential of the Gr-ZnO hybrid nanocomposites as an electrode in high-performance supercapacitors. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:544 / 550
页数:7
相关论文
共 38 条
[1]   Micro-Raman investigation of optical phonons in ZnO nanocrystals [J].
Alim, KA ;
Fonoberov, VA ;
Shamsa, M ;
Balandin, AA .
JOURNAL OF APPLIED PHYSICS, 2005, 97 (12)
[2]   Incorporation of graphene in quantum dot sensitized solar cells based on ZnO nanorods [J].
Chen, Jing ;
Li, Chu ;
Eda, Goki ;
Zhang, Yan ;
Lei, Wei ;
Chhowalla, Manish ;
Milne, William I. ;
Deng, Wei-Qiao .
CHEMICAL COMMUNICATIONS, 2011, 47 (21) :6084-6086
[3]   High performance of a solid-state flexible asymmetric supercapacitor based on graphene films [J].
Choi, Bong Gill ;
Chang, Sung-Jin ;
Kang, Hyun-Wook ;
Park, Chan Pil ;
Kim, Hae Jin ;
Hong, Won Hi ;
Lee, SangGap ;
Huh, Yun Suk .
NANOSCALE, 2012, 4 (16) :4983-4988
[4]   Theory of Ragone plots [J].
Christen, T ;
Carlen, MW .
JOURNAL OF POWER SOURCES, 2000, 91 (02) :210-216
[5]   One dimensional MnO2/titanium nitride nanotube coaxial arrays for high performance electrochemical capacitive energy storage [J].
Dong, Shanmu ;
Chen, Xiao ;
Gu, Lin ;
Zhou, Xinhong ;
Li, Lanfeng ;
Liu, Zhihong ;
Han, Pengxian ;
Xu, Hongxia ;
Yao, Jianhua ;
Wang, Haibo ;
Zhang, Xiaoying ;
Shang, Chaoqun ;
Cui, Guanglei ;
Chen, Liquan .
ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (09) :3502-3508
[6]   Laser Scribing of High-Performance and Flexible Graphene-Based Electrochemical Capacitors [J].
El-Kady, Maher F. ;
Strong, Veronica ;
Dubin, Sergey ;
Kaner, Richard B. .
SCIENCE, 2012, 335 (6074) :1326-1330
[7]   Sandwiched nanoarchitecture of reduced graphene oxide/ZnO nanorods/reduced graphene oxide on flexible PET substrate for supercapacitor [J].
Guo, Guilve ;
Huang, Lei ;
Chang, Quanhong ;
Ji, Lechun ;
Liu, Yang ;
Xie, Yiqun ;
Shi, Wangzhou ;
Jia, Nengqin .
APPLIED PHYSICS LETTERS, 2011, 99 (08)
[8]   Highly conductive paper for energy-storage devices [J].
Hu, Liangbing ;
Choi, Jang Wook ;
Yang, Yuan ;
Jeong, Sangmoo ;
La Mantia, Fabio ;
Cui, Li-Feng ;
Cui, Yi .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2009, 106 (51) :21490-21494
[9]   PREPARATION OF GRAPHITIC OXIDE [J].
HUMMERS, WS ;
OFFEMAN, RE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (06) :1339-1339
[10]  
Jayalakshmi M, 2008, INT J ELECTROCHEM SC, V3, P96