Organocatalytic C-H/C-H′ Cross-Biaryl Coupling: C-Selective Arylation of Sulfonanilides with Aromatic Hydrocarbons

被引：127
|
作者：
Ito, Motoki [1 ]
Kubo, Hiroko [1 ]
Itani, Itsuki [1 ]
Morimoto, Koji [1 ]
Dohi, Toshifumi [1 ]
Kita, Yasuyuki [1 ]
机构：
[1] Ritsumeikan Univ, Coll Pharmaceut Sci, Kusatsu, Shiga 5258577, Japan
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2013年 / 135卷 / 38期
基金：
日本学术振兴会;
关键词：
CATALYZED ORTHO-ARYLATION; BOND FORMATION; ANILIDES; ARENES; FUNCTIONALIZATION;
D O I：
10.1021/ja407944p
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The hypervalent iodine-mediated C-C selective coupling of N-methanesulfonyl anilides with aromatic hydrocarbons has been developed. The first organocatalytic oxidative cross-biaryl-coupling was achieved by the catalyst control in defining specific 2,2'-diiodobiphenyls for the direct C-C bond formations.
引用
收藏
页码：14078 / 14081
页数：4
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