Palladium-Catalyzed Carbonylation in the Synthesis of N-Ynonylsulfoximines

被引：16

作者：

Ma, Ding ^{[1
]}

Wang, Chenyang ^{[1
]}

Kong, Deshen ^{[1
]}

Tu, Yongliang ^{[1
]}

Shi, Peng ^{[1
]}

Bolm, Carsten ^{[1
]}

机构：

[1] Rhein Westfal TH Aachen, Inst Organ Chem, Landoltweg 1, D-52074 Aachen, Germany

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2021年 / 363卷 / 05期

关键词：

carbonylation; chromium hexacarbonyl; palladium catalysis; sulfoximines; ynones; CHEMICAL CHAMELEONS; CARBON-MONOXIDE; SULFOXIMINES; ARYL; AMINOCARBONYLATION; HETEROCYCLES; PERSPECTIVE; CHEMISTRY; ALKYNES; AMINES;

D O I：

10.1002/adsc.202001440

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Palladium-catalyzed carbonylation reactions with Cr(CO)(6) as carbonyl source are key for the preparation of N-ynonylsulfoximines from NH-sulfoximines and bromoalkynes. The couplings proceed at room temperature with a wide range of substrate combinations affording the corresponding products in good yields.

引用

页码：1330 / 1334

页数：5

共 54 条

[1] Chiral Analogues of PFI-1 as BET Inhibitors and Their Functional Role in Myeloid Malignancies [J].

Altenburg, Bianca ;

Frings, Marcus ;

Schoebel, Jan-Hendrik ;

Gossen, Jonas ;

Pannen, Kristina ;

Vanderliek, Kim ;

Rossetti, Giulia ;

Koschmieder, Steffen ;

Chatain, Nicolas ;

Bolm, Carsten .

ACS MEDICINAL CHEMISTRY LETTERS, 2020, 11 (10) :1928-1934

[2]

[Anonymous], 2011, ANGEW CHEM INT ED, V50, P10788

[3]

[Anonymous], 2009, ANGEW CHEM INT ED, V48, P4114

[4]

[Anonymous], 2009, ANGEW CHEM, DOI 10.1002/ange.200900013

[5] Development of a Scalable Process for the Crop Protection Agent Isoclast [J].

Arndt, Kim E. ;

Bland, Douglas C. ;

Irvine, Nicholas M. ;

Powers, Stacey L. ;

Martin, Timothy P. ;

McConnell, James Russell ;

Podhorez, David E. ;

Renga, James M. ;

Ross, Ronald ;

Roth, Gary A. ;

Scherzer, Brian D. ;

Toyzan, Todd W. .

ORGANIC PROCESS RESEARCH & DEVELOPMENT, 2015, 19 (03) :454-462

[6]

Bacci L., 2018, Journal of Entomological and Acarological Research, V50, P51, DOI 10.4081/jear.2018.7836

[7] Sulfoximinocarbonylation of aryl halides using heterogeneous Pd/C catalyst [J].

Bala, Balasubramanian Devi ;

Sharma, Nidhi ;

Sekar, Govindasamy .

RSC ADVANCES, 2016, 6 (99) :97152-97159

[8] Synthesis of Novel Aryl and Heteroaryl Acyl Sulfonimidamides via Pd-Catalyzed Carbonylation Using a Nongaseous Precursor [J].

Borhade, Sanjay R. ;

Sandstrom, Anja ;

Arvidsson, Per I. .

ORGANIC LETTERS, 2013, 15 (05) :1056-1059

[9] BN- and BO-Doped Inorganic-Organic Hybrid Polymers with Sulfoximine Core Units [J].

Brosge, Felix ;

Lorenz, Thomas ;

Helten, Holger ;

Bolm, Carsten .

CHEMISTRY-A EUROPEAN JOURNAL, 2019, 25 (55) :12708-12711

[10] Straightforward Strategies for the Preparation of NH-Sulfoximines: A Serendipitous Story [J].

Bull, James A. ;

Degennaro, Leonardo ;

Luisi, Renzo .

SYNLETT, 2017, 28 (19) :2525-2538

← 1 2 3 4 5 6 →