Stabilization of mesoporous molecular sieves by trimethylsilylation

被引:270
作者
Koyano, KA
Tatsumi, T
Tanaka, Y
Nakata, S
机构
[1] UNIV TOKYO,SCH ENGN,ENGN RES INST,TOKYO 113,JAPAN
[2] CHIYODA CORP,KANAGAWA KU,YOKOHAMA,KANAGAWA 221,JAPAN
来源
JOURNAL OF PHYSICAL CHEMISTRY B | 1997年 / 101卷 / 46期
关键词
D O I
10.1021/jp9724941
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The stability of Si-MCM-48 to moisture and compression can be improved by trimethylsilylation, as a result of the increase in hydrophobicity. Moreover, the stability is retained after calcination, although the calcined material is no longer hydrophobic. This stabilizing effect was also observed for Si-MCM-41 and Ti-MCM-41.
引用
收藏
页码:9436 / 9440
页数:5
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