Identification of non-volatile migrants from baby bottles by UPLC-Q-TOF-MS

被引：13
|
作者：
Oliveira, Wellington da Silva [1 ]
Ubeda, Sara [2 ]
Nerin, Cristina [2 ]
Padula, Marisa [3 ]
Godoy, Helena Teixeira [1 ]
机构：
[1] Univ Campinas UNICAMP, Sch Food Engn, Dept Food Sci, Campinas, SP, Brazil
[2] Univ Zaragoza, Aragon Inst Engn Res I3A, GUIA Grp, Dept Analyt Chem, Zaragoza, Spain
[3] Inst Food Technol ITAL, Packaging Technol Ctr, Campinas, SP, Brazil
来源：
FOOD RESEARCH INTERNATIONAL | 2019年 / 123卷
基金：
巴西圣保罗研究基金会;
关键词：
Silicone; Tritan; Migration; Baby bottles; Q-TOF; Risk assessment; FOOD CONTACT MATERIALS; RISK-ASSESSMENT; HEALTH-RISKS; SUBSTANCES; MIGRATION; QUANTIFICATION; CHEMICALS; EXTRACTION; EFFICIENCY; ADHESIVES;
D O I：
10.1016/j.foodres.2019.05.012
中图分类号：
TS2 [食品工业];
学科分类号：
0832 ;
摘要：
Baby bottles made of polypropylene, Tritan (R) and silicone were evaluated regarding the migration of non-volatile compounds using UPLC-QTOF-MS. Twenty-seven compounds were identified. In all polypropylene samples the migration of 2.2'-(tridecylimino)bis-ethanol and derivatives thereof were detected in concentrations below the specific migration limit (1.2 mg.kg(-1)). Furthermore, clarifying agents and glycerol derivatives were detected. Tritan baby bottle showed the migration of one slip additive. On the other hand, twenty compounds were detected in silicone baby bottles. Most of them were unknown compounds derived from acrylates. Once the migrants were identified, the risk assessment was carried out using the Threshold of Toxicological Concern (TTC) approach. The risk assessment of migrants coming from silicone samples showed levels above the threshold recommended as safe for babies.
引用
收藏
页码：529 / 537
页数：9
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