Chemoselective Oxidation of Sulfides to Sulfoxides with Urea-Hydrogen Peroxide Complex Catalysed by Diselenide

被引：19

作者：

Page, Philip C. Bulman ^{[1
]}

Buckley, Benjamin R. ^{[2
]}

Elliott, Claire ^{[2
]}

Chan, Yohan ^{[1
]}

Dreyfus, Nicolas ^{[3
]}

Marken, Frank ^{[4
]}

机构：

[1] Univ E Anglia, Sch Chem, Norwich NR4 7TJ, Norfolk, England

[2] Univ Loughborough, Dept Chem, Loughborough LE11 3TU, Leics, England

[3] Lilly Res Ctr, Windlesham KT13 8JT, Surrey, England

[4] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

来源：

SYNLETT | 2016年 / 27卷 / 01期

关键词：

sulfoxidation; urea-hydrogen peroxide; diphenyl diselenide; oxidation; catalysis; BAEYER-VILLIGER OXIDATION; SELECTIVE OXIDATION; AROMATIC-ALDEHYDES; CRYSTAL-STRUCTURE; ALLYLIC ALCOHOLS; EPOXIDATION; EFFICIENT; ALKENES; KETONES; ACIDS;

D O I：

10.1055/s-0034-1378827

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A highly selective catalytic oxidation system has been developed for the conversion of sulfides into the corresponding sulfoxides using urea-hydrogen peroxide as stoichiometric oxidant in the presence of a catalytic quantity of diphenyl diselenide.

引用

页码：80 / 82

页数：3

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