Syntheses and Characterization of Cyanide-Bridged Bimetallic Compounds Zn(terpy)(H2O)M(CN)4 (terpy=2,2′:6′,2"-terpyridine; M = Ni, Pd, Pt) with Linear Chains

被引：5
|
作者：
Chen, Ying-Ying [1 ]
Hu, Ai-Yun [1 ]
Shen, Meng-Qi [2 ]
Tian, Xiao-Yan [1 ]
Zhou, Hu [3 ,4 ]
机构：
[1] Jiangsu Univ Sci & Technol, Sch Environm & Chem Engn, Zhenjiang 212003, Peoples R China
[2] Jilin Univ, Coll Chem, Changchun 130012, Peoples R China
[3] Jiangsu Univ Sci & Technol, Sch Mat Sci & Engn, Zhenjiang 212003, Peoples R China
[4] SiYang Diesel Engine Mfg Co Ltd, Zhenjiang 212003, Peoples R China
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2014年 / 640卷 / 11期
基金：
中国国家自然科学基金;
关键词：
Tetracyanometalates; Syntheses; Linear chain; Zinc; X-ray diffraction; Thermal stability; MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURES; BUILDING-BLOCKS; COMPLEXES; FE; ASSEMBLIES; CHEMISTRY; ADSORPTION; LIGAND; CU(II);
D O I：
10.1002/zaac.201400196
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The self-assembly reaction of zinc ions with tetracyanometalates in the presence of the tridentate chelated ligand 2,2:6,2-terpyridine (terpy) yielded three cyanide-bridged bimetallic compounds of general formula Zn(terpy)(H2O)M(CN)(4) [M = Ni (1), Pd (2), Pt (3)]. Compounds 1-3 were characterized by X-ray diffraction (XRD), infrared spectroscopy (IR), and thermogravimetric (TG) analysis. Single-crystal XRD analysis revealed that compounds 1-3 are isostructural and the structure consists of [Zn(terpy)(H2O)](2+) moieties and [M(CN)(4)](2-) units linked alternatively to generate a one-dimensional (1D) linear chain. The chains are further connected together through hydrogen bonding and - stacking interactions, forming a 3D supramolecular network. IR spectroscopic analysis indicated the presence of cyanide groups and terpy ligands in the structure. TG and powder XRD results showed that compounds 1-3 have higher thermal stabilities and exhibited irreversible for desorption/resorption of one coordinated water molecule.
引用
收藏
页码：2287 / 2291
页数：5
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