Selective determination of trace bisphenol a using molecularly imprinted silica nanoparticles containing quenchable fluorescent silver nanoclusters

被引:26
作者
Deng, Chun [2 ]
Zhong, Yaping [2 ]
He, Yu [1 ,2 ]
Ge, Yili [1 ,2 ]
Song, Gongwu [1 ,2 ]
机构
[1] Hubei Univ, Hubei Collaborat Innovat Ctr Adv Organ Chem Mat, Wuhan 430062, Peoples R China
[2] Hubei Univ, Coll Chem & Chem Engn, Minist Educ, Key Lab Synth & Applicat Organ Funct Mol, Wuhan 430062, Peoples R China
关键词
Molecular imprint; Silver nanoclusters; Fluorescence; Quenching; Milk analysis; HIGHLY SENSITIVE DETECTION; SOLID-PHASE EXTRACTION; GOLD NANOCLUSTERS; QUANTUM DOTS; HUMAN URINE; PROBE; SENSOR; RECOGNITION; SAMPLES; WATER;
D O I
10.1007/s00604-015-1662-x
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
We describe a kind of molecularly imprinted polymer (MIP)-based fluorescent sensor. It was obtained by anchoring a surface-imprinted MIP layer for the model analyte bisphenol A (BPA) onto the surface of fluorescent silver nanoclusters (Ag-NCs). The MIP-coated Ag-NCs were synthesized by the sol-gel technique. The hyphenation of the fluorescence of Ag-NCs with MIP technology expands the use of fluorescent nanomaterials in sensing and recognition. BPA is capable of quenching the fluorescence of the Ag-NCs, and the reduction in fluorescence intensity is related to the concentration of BPA in the 0.2 mu g mL(-1) to 2 mg L-1 range. The detection limit for BPA is 0.02 mu g mL(-1), and the recovery of BPA from spiked milk and juice samples ranged from 92.5 to 108.5 %. The MIP-coated Ag-NCs presented here are characterized by their ease of synthesis, selectivity and sensitivity. In our perception, this approach can be extended to numerous other analytes.
引用
收藏
页码:431 / 439
页数:9
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