A facile and efficient method for preparing ring-alkylated vanadocenes (RCp)(2)V and mono- and dichlorides of ring-alkylated vanadocenes (RCp)(2)VCl and (RCp)(2)VCl2

被引:13
作者
Belot, JA
McCullough, RD
Rheingold, AL
Yap, GPA
机构
[1] CARNEGIE MELLON UNIV,DEPT CHEM,PITTSBURGH,PA 15213
[2] UNIV DELAWARE,DEPT CHEM,NEWARK,DE 19716
关键词
D O I
10.1021/om960349o
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A convenient procedure for the general preparation of bis(methylcyclopentadienyl)vanadium (1), bis(isopropylcyclopentadienyl)vanadium (2), and bis(tert-butylcylopentadienyl)vanadium (3) and their blue monochloride (4-6) and green dichloride (7-9) derivatives is presented. The X-ray structures of compounds 8 and 9 and the electrochemistry and EPR of 7-9 are also presented.
引用
收藏
页码:5062 / 5065
页数:4
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