A facile and efficient method for preparing ring-alkylated vanadocenes (RCp)(2)V and mono- and dichlorides of ring-alkylated vanadocenes (RCp)(2)VCl and (RCp)(2)VCl2

被引：13

作者：

Belot, JA

McCullough, RD

Rheingold, AL

Yap, GPA

机构：

[1] CARNEGIE MELLON UNIV,DEPT CHEM,PITTSBURGH,PA 15213

[2] UNIV DELAWARE,DEPT CHEM,NEWARK,DE 19716

来源：

ORGANOMETALLICS | 1996年 / 15卷 / 23期

关键词：

D O I：

10.1021/om960349o

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A convenient procedure for the general preparation of bis(methylcyclopentadienyl)vanadium (1), bis(isopropylcyclopentadienyl)vanadium (2), and bis(tert-butylcylopentadienyl)vanadium (3) and their blue monochloride (4-6) and green dichloride (7-9) derivatives is presented. The X-ray structures of compounds 8 and 9 and the electrochemistry and EPR of 7-9 are also presented.

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页码：5062 / 5065

页数：4

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