Experimental and Theoretical Advances on Single Atom and Atomic Cluster-Decorated Low-Dimensional Platforms towards Superior Electrocatalysts

被引：44

作者：

He, Tianwei ^{[1
]}

Puente-Santiago, Alain R. ^{[2
]}

Xia, Shiyu ^{[3
,4
]}

Ahsan, Md Ariful ^{[2
]}

Xu, Guobao ^{[3
,4
]}

Luque, Rafael ^{[5
,6
]}

机构：

[1] Fritz Haber Inst Max Planck Gesell, Faradayweg 4-6, D-14195 Berlin, Germany

[2] Univ Texas El Paso, Dept Chem, 500 West Univ Ave, El Paso, TX 79968 USA

[3] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Elect Chem, Changchun 130022, Jilin, Peoples R China

[4] Univ Sci & Technol China, Hefei 230026, Anhui, Peoples R China

[5] Univ Cordoba, Dept Organ Chem, Campus Rabanales,Edificio Marie Curie C-3,Ctra, E-14014 Cordoba, Spain

[6] RUDN Univ, Peoples Friendship Univ Russia, 6 Miklukho Maklaya str, Moscow 117198, Russia

来源：

ADVANCED ENERGY MATERIALS | 2022年 / 12卷 / 22期

基金：

中国国家自然科学基金;

关键词：

electrochemical devices; energy conversion; low-dimensional nanomaterials; low nuclearity catalysts; OXYGEN REDUCTION REACTION; GRAPHITIC CARBON NITRIDE; DUAL-METAL SITES; CATALYTIC PERFORMANCE; CONFINED CATALYSIS; DOPED GRAPHENE; CO2; REDUCTION; HYDROGEN; SUBNANOMETER; NANOSHEETS;

D O I：

10.1002/aenm.202200493

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The fundamental relationship between structure and properties, which is called "structure-property", plays a vital role in the rational designing of high-performance catalysts for diverse electrocatalytic applications. Low-dimensional (LD) nanomaterials, including 0D, 1D, 2D materials, combined with low-nuclearity metal atoms, ranging from single atoms to subnanometer clusters, are currently emerging as rising star nanoarchitectures for heterogeneous catalysis due to their well-defined active sites and unbeatable metal utilization efficiencies. In this work, a comprehensive experimental and theoretical review is provided on the recent development of single atom and atomic cluster-decorated LD platforms towards some typical clean energy reactions, such as water-splitting, nitrogen fixation, and carbon dioxide reduction reactions. The upmost attractive structural properties, advanced characterization techniques, and theoretical principles of these low-nuclearity electrocatalysts as well as their applications in key electrochemical energy devices are also elegantly discussed.

引用

页数：28