Ionic self-assembly affords mesoporous ionic networks by crosslinking linear polyviologens with polyoxometalate clusters

被引：20
作者：
Chen, Guojian [1 ,2 ]
Hou, Wei [1 ]
Li, Jing [1 ]
Wang, Xiaochen [1 ]
Zhou, Yu [1 ]
Wang, Jun [1 ]
机构：
[1] Nanjing Tech Univ, Coll Chem Engn, State Key Lab Mat Oriented Chem Engn, Nanjing 210009, Jiangsu, Peoples R China
[2] Jiangsu Normal Univ, Sch Chem & Chem Engn, Xuzhou 221116, Peoples R China
来源：
DALTON TRANSACTIONS | 2016年 / 45卷 / 11期
基金：
中国国家自然科学基金;
关键词：
HETEROGENEOUS CATALYST; 2,5-DIFORMYLFURAN; FRAMEWORKS; OXIDATION; NANOPARTICLES; HYBRID;
D O I：
10.1039/c6dt00070c
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Ionic-bonded mesoporous ionic networks were prepared by the ionic self-assembly of polyoxometalate (POM) clusters with linear cationic polyviologens in water. The POM-enriched PMIN-2(V) possesses a high surface area up to 120 m(2) g(-1), exhibiting superior non-noble metal heterogeneous catalytic performance in the ambient aerobic selective oxidation of 5-hydroxymethylfurfural.
引用
收藏
页码：4504 / 4508
页数：5
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