The Carbanionic Phosphoylide Dianion [PhP(CH2)3]2-, Isoelectronic with Phosphonate Dianions [RP(O)3]2-

被引：6
|
作者：
Less, Robert J. [1 ]
Naseri, Vesal [1 ]
Wright, Dominic S. [1 ]
机构：
[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England
来源：
ORGANOMETALLICS | 2009年 / 28卷 / 13期
基金：
英国工程与自然科学研究理事会;
关键词：
CRYSTAL-STRUCTURE; COORDINATION; CAGES;
D O I：
10.1021/om9001704
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Deprotonation of [PhP(CH3)(3)](+) [I](-) with (BuLi)-Bu-t gives [Li-2{PhP(CH2)(3))}center dot 2thf](2) (1), whose [PhP(CH2)(3)](2-) anions is isoelectronic with the phosphonate dianion [RP(O)(3)](2-).
引用
收藏
页码：3594 / 3596
页数：3
相关论文
共 50 条
  • [31] Synthesis and spectroscopic characterization of the heterosilylated anions [PW9O34(tBuSiO)3(SiR)]3- (R = -CH3, -CH=CH2, -CH2-CH=CH2, -(CH2)4-CH=CH2) -: X-ray crystal structure of [nBu4N]3[PW9O34(tBuSiO)3(SiCH2-CH=CH2)]
    Agustin, D
    Coelho, C
    Mazeaud, A
    Herson, P
    Proust, A
    Thouvenot, R
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2004, 630 (12): : 2049 - 2053
  • [32] Preparation of New Derivatives of the closo-Dodecaborate Anion [B12H10(OC(O)CH3){OC(O)(CH2)3CH3}]2–, [B12H10(OH){OC(O)(CH2)3CH3}]2–, [B12H10(SCN){OC(O)(CH2)3CH3}]2–, and [B12H10(I){OC(O)(CH2)3CH3}]2–
    L. V. Gorobinskii
    K. A. Solntsev
    N. T. Kuznetsov
    Russian Journal of Coordination Chemistry, 2002, 28 : 451 - 453
  • [33] Co(NO3)2-(CH3)2SO-H2O system at 25°C
    E. A. Frolova
    E. A. Makeeva
    V. T. Orlova
    V. P. Danilov
    Russian Journal of Inorganic Chemistry, 2009, 54 : 2002 - 2004
  • [34] THE X-RAY CRYSTAL STRUCTURES OF THE [Mo2(V)O2S(OCOCH(S)CH3)3]2- AND [Mo2(V)O2S2 (OCOCH(S)CH3)2]2-
    Liu-Gonzalez, M.
    Sanz-Ruiz, F.
    Sanz-Persiva, V.
    Palanca-Alandes, P.
    Garcia Rodriguez, Esther
    Garcia-Granda, S.
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 1999, 55 : 430 - 430
  • [35] UNIMOLECULAR REACTIONS OF ISOLATED ORGANIC IONS - THE CHEMISTRY OF THE OXONIUM IONS CH3CH2CH2CH2+O = CH2 AND CH3CH2CH2CH = O+CH3
    BOWEN, RD
    DERRICK, PJ
    ORGANIC MASS SPECTROMETRY, 1993, 28 (10): : 1197 - 1209
  • [36] STRUCTURE OF [NH3-(CH2)2-NH-(CH2)2-NH3]2P4O12.4H2O
    BDIRI, M
    JOUINI, A
    EUROPEAN JOURNAL OF SOLID STATE AND INORGANIC CHEMISTRY, 1989, 26 (06): : 585 - 592
  • [37] Excess molar volumes of {x(1)CH(3)CH(2)COOCH(2)CH(3)+x(2)CH(3)(CH2)(4)CH3+(1-x(1)-x(2))CH3(CH2)(2)OH or CH3(CH2)(3)OH} at the temperature 298.15 K
    Jimenez, E
    Franjo, C
    Menaut, CP
    Segade, L
    Legido, JL
    Andrade, MIP
    JOURNAL OF CHEMICAL THERMODYNAMICS, 1997, 29 (02): : 117 - 124
  • [38] Syntheses and Structures of Two New Borates: [NH3(CH2)3N(CH2)4N(CH2)3NH3][B5O6(OH)4]2 and [NH2(CH2)4N(CH2)2NH3][B7O10(OH)3]
    Wu, Lian-Zhi
    Cheng, Lin
    Yang, Guo-Yu
    JOURNAL OF CLUSTER SCIENCE, 2013, 24 (03) : 811 - 820
  • [39] UNIMOLECULAR REACTIONS OF ISOLATED ORGANIC IONS - REACTIONS OF THE IMMONIUM IONS CH2=N+(CH3)CH(CH3)2, CH2=N+(CH3)CH2CH2CH3 AND CH2=N+(CH2CH2CH3)2
    BOWEN, RD
    COLBURN, AW
    DERRICK, PJ
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1993, (12): : 2363 - 2372
  • [40] Syntheses and Structures of Two New Borates: [NH3(CH2)3N(CH2)4N(CH2)3NH3][B5O6(OH)4]2 and [NH2(CH2)4N(CH2)2NH3][B7O10(OH)3]
    Lian-Zhi Wu
    Lin Cheng
    Guo-Yu Yang
    Journal of Cluster Science, 2013, 24 : 811 - 820
12345