The Carbanionic Phosphoylide Dianion [PhP(CH2)3]2-, Isoelectronic with Phosphonate Dianions [RP(O)3]2-

被引：6
|
作者：
Less, Robert J. [1 ]
Naseri, Vesal [1 ]
Wright, Dominic S. [1 ]
机构：
[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England
来源：
ORGANOMETALLICS | 2009年 / 28卷 / 13期
基金：
英国工程与自然科学研究理事会;
关键词：
CRYSTAL-STRUCTURE; COORDINATION; CAGES;
D O I：
10.1021/om9001704
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Deprotonation of [PhP(CH3)(3)](+) [I](-) with (BuLi)-Bu-t gives [Li-2{PhP(CH2)(3))}center dot 2thf](2) (1), whose [PhP(CH2)(3)](2-) anions is isoelectronic with the phosphonate dianion [RP(O)(3)](2-).
引用
收藏
页码：3594 / 3596
页数：3
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