Luminescent chemosensors by using cyclometalated iridium(III) complexes and their applications

被引：199
作者：
Ma, Dik-Lung [1 ]
Lin, Sheng [1 ]
Wang, Wanhe [1 ]
Yang, Chao [2 ]
Leung, Chung-Hang [2 ]
机构：
[1] Hong Kong Baptist Univ, Dept Chem, Kowloon Tong, Hong Kong, Peoples R China
[2] Univ Macau, Inst Chinese Med Sci, State Key Lab Qual Res Chinese Med, Macau, Peoples R China
来源：
CHEMICAL SCIENCE | 2017年 / 8卷 / 02期
基金：
中国国家自然科学基金;
关键词：
RESOLVED PHOTOLUMINESCENCE SPECTROSCOPY; CRYSTAL MICROBALANCE BIOSENSOR; TRANSITION-METAL-COMPLEXES; SINGLET OXYGEN SENSITIZERS; SELECTIVE DETECTION; IN-VIVO; PHOSPHORESCENT CHEMODOSIMETER; FLUORESCENT CHEMOSENSOR; PLATINUM(II) COMPLEXES; MOLECULAR-OXYGEN;
D O I：
10.1039/c6sc04175b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Luminescent metal complexes have found increasing use in multiple areas of science and technology, including in chemosensing, light-emitting devices and photochemistry. In particular, the use of cyclometalated iridium(III) complexes as chemosensors has received increasing attention in the recent literature. Phosphorescent metal complexes enjoy a number of advantages (e.g., long-lived phosphorescence, high quantum efficiency and modular syntheses) that render them as suitable alternatives to organic dyes for sensing a variety of analytes. This review describes recent examples of cyclometalated iridium(III) complexes that act as luminescent chemosensors for cations, anions or small molecules.
引用
收藏
页码：878 / 889
页数：12
相关论文
共 84 条
[1]   Highly Selective Detection of H+ and OH- with a Single-Emissive Iridium(III) Complex: A Mild Approach to Conversion of Non-AIEE to AIEE Complex [J].
Alam, Parvej ;
Kaur, Gurpreet ;
Sarmah, Amrit ;
Roy, Ram Kinkar ;
Choudhury, Angshuman Roy ;
Laskar, Inamur Rahaman .
ORGANOMETALLICS, 2015, 34 (18) :4480-4490
[2]   Highly sensitive explosive sensing by "aggregation induced phosphorescence'' active cyclometalated iridium(III) complexes [J].
Alam, Parvej ;
Kaur, Gurpreet ;
Kachwal, Vishal ;
Gupta, Asish ;
Choudhury, Angshuman Roy ;
Laskar, Inamur Rahaman .
JOURNAL OF MATERIALS CHEMISTRY C, 2015, 3 (21) :5450-5456
[3]   New 'aggregation induced emission (AIE)' active cyclometalated iridium(III) based phosphorescent sensors: high sensitivity for mercury(II) ions [J].
Alam, Parvej ;
Kaur, Gurpreet ;
Climent, Claudia ;
Pasha, Saleem ;
Casanova, David ;
Alemany, Pere ;
Choudhury, Angshuman Roy ;
Laskar, Inamur Rahaman .
DALTON TRANSACTIONS, 2014, 43 (43) :16431-16440
[4]  
[Anonymous], 2013, MATH PROBL ENG, DOI DOI 10.1371/J0URNAL.P0NE.0053916
[5]   Time-Resolved Emission Imaging Microscopy Using Phosphorescent Metal Complexes: Taking FLIM and PLIM to New Lengths [J].
Baggaley, Elizabeth ;
Weinstein, Julia A. ;
Williams, J. A. Gareth .
LUMINESCENT AND PHOTOACTIVE TRANSITION METAL COMPLEXES AS BIOMOLECULAR PROBES AND CELLULAR REAGENTS, 2015, 165 :205-256
[6]   A Highly Selective Chemosensor for Cyanide Derived from a Formyl-Functionalized Phosphorescent Iridium(III) Complex [J].
Bejoymohandas, K. S. ;
Kumar, Ajay ;
Sreenadh, S. ;
Varathan, E. ;
Varughese, S. ;
Subramanian, V. ;
Reddy, M. L. P. .
INORGANIC CHEMISTRY, 2016, 55 (07) :3448-3461
[7]   A sulfur-free iridium(III) complex for highly selective and multi-signaling mercury(II)-chemosensors [J].
Cao, Hong-Tao ;
Ding, Lei ;
Shan, Guo-Gang ;
Sun, Hai-Zhu ;
Wu, Yong ;
Su, Zhong-Min .
DALTON TRANSACTIONS, 2015, 44 (46) :19997-20003
[8]   Anion recognition and sensing by transition-metal complexes with polarized N-H recognition motifs [J].
Chang, Kai-Chi ;
Sun, Shih-Sheng ;
Odago, Maurice O. ;
Lees, Alistair J. .
COORDINATION CHEMISTRY REVIEWS, 2015, 284 :111-123
[9]   Selective phosphorescence chemosensor for homocysteine based on an iridium(III) complex [J].
Chen, Huili ;
Zhao, Qiang ;
Wu, Yanbo ;
Li, Fuyou ;
Yang, Hong ;
Yi, Tao ;
Huang, Chunhui .
INORGANIC CHEMISTRY, 2007, 46 (26) :11075-11081
[10]   Fluorescent and colorimetric probes for detection of thiols [J].
Chen, Xiaoqiang ;
Zhou, Ying ;
Peng, Xiaojun ;
Yoon, Juyoung .
CHEMICAL SOCIETY REVIEWS, 2010, 39 (06) :2120-2135
123456789