Substituent effects of phenylboronic acid-functionalized resins in pH-controlled separation of catecholic flavonoids

被引：8

作者：

Lee, Sang Min ^{[1
]}

Chung, Jinhyo ^{[1
]}

Gong, Mi Sic ^{[1
]}

Jun, Bong-Hyun ^{[2
]}

Kweon, Dae-Hyuk ^{[1
]}

Chung, Woo-Jae ^{[1
]}

机构：

[1] Sungkyunkwan Univ Suwon, Dept Integrat Biotechnol, Gyeonggi Do 16419, South Korea

[2] Konkuk Univ, Dept Biosci & Biotechnol, Seoul 143701, South Korea

来源：

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY | 2019年 / 77卷

关键词：

Phenylboronic acid; Flavonoid; Quercetin; Solid-supported reagent; pH-controlled separation; ADSORPTION; AMINO;

D O I：

10.1016/j.jiec.2019.04.031

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Gel resins modified with different phenylboronic acid derivatives were prepared for selective separation of catechol-containing flavonoids. The phenylboronic acid gel (PBA-gel) resins showed pH-dependent adsorption and release of catechol-containing flavonoid quercetin. Under optimal pH control, the PBA-gel resins exhibited high quercetin binding capacity of up to 120 mg/g of resin and demonstrate quantitative release of the specifically bound quercetin. In addition, the recyclability of PBA-gel resin was confirmed by repeated binding and hydrolysis of quercetin with no significant loss of capacity during at least five cycles, showing great potential of PBA-gels as practical tools for selective separation of catechol-containing flavonoids. (C) 2019 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.

引用

页码：164 / 170

页数：7

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