Modeling the dynamics of membrane structure formation in quenched polymer solutions

被引：28

作者：

Barton, BF ^{[1
]}

McHugh, AJ ^{[1
]}

机构：

[1] Univ Illinois, Dept Chem Engn, Urbana, IL 61801 USA

来源：

JOURNAL OF MEMBRANE SCIENCE | 2000年 / 166卷 / 01期

基金：

美国国家科学基金会;

关键词：

membrane formation; theory; phase inversion;

D O I：

10.1016/S0376-7388(99)00257-4

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Calculations are presented to illustrate the use of droplet growth rate data, obtained from light scattering measurements and/or spinodal decomposition calculations, to model the evolution of pore size gradients in solutions undergoing temperature-induced (TIPS) phase inversion. A simplified one-dimensional heat transport equation is used to obtain transient temperature profiles in quenched thin films, and these are combined with pore growth rates as a function of temperature and composition, to quantify droplet (i.e. pore) sizes in the final membrane. Results demonstrate the effects of quench temperature on the transient and final pore size distribution in the quenched films. (C)2000 Elsevier Science B.V. All rights reserved.

引用

页码：119 / 125

页数：7

共 23 条

[1] Dynamics of spinodal decomposition in polymer solutions near a glass transition [J].