Polymer-supported ferrocenyl oxazolines for the catalyzed highly enantioselective phenyl transfer to aldehydes

被引：46

作者：

Bolm, C ^{[1
]}

Hermanns, N ^{[1
]}

Classen, A ^{[1
]}

Muñiz, K ^{[1
]}

机构：

[1] Rhein Westfal TH Aachen, Inst Organ Chem, D-52056 Aachen, Germany

来源：

BIOORGANIC & MEDICINAL CHEMISTRY LETTERS | 2002年 / 12卷 / 14期

关键词：

D O I：

10.1016/S0960-894X(02)00271-8

中图分类号：

R914 [药物化学];

学科分类号：

100701 ;

摘要：

A new chiral MeO-PEG-supported ferrocenyl oxazoline was synthesized and successfully employed in the enantioselective phenyl transfer to aldehydes. The products were obtained in high yields and with excellent enantioselectivities (up to 97% ee). Furthermore, the recovery of the ferrocene was facile, and catalyst efficiency was maintained in subsequent reactions. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：1795 / 1798

页数：4

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