2-Hydroxy-1,10-phenanthroline vs 1,10-Phenanthroline: Significant Ligand Acceleration Effects in the Palladium-Catalyzed Oxidative Heck Reaction of Arenes

被引：74

作者：

Ying, Cheng-Hao ^{[1
]}

Yan, Shao-Bai ^{[1
]}

Duan, Wei-Liang ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

来源：

ORGANIC LETTERS | 2014年 / 16卷 / 02期

关键词：

C-H OLEFINATION; REVERSIBLE DEHYDROGENATION-HYDROGENATION; DIRECT ARYLATION; BOND FORMATION; PD CATALYSTS; C3-SELECTIVE ARYLATION; FUNCTIONALIZATION; ACTIVATION; PYRIDINES; COMPLEXES;

D O I：

10.1021/ol4033804

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of bidentate monoanionic nitrogen ligands were designed and applied in the Pd-catalyzed oxidative Heck reaction of arenes with alkenes. Significant ligand-accelerated effects were observed, and direct C-H functionalized products were formed in high yields with meta-selectivity.

引用

页码：500 / 503

页数：4

共 66 条

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